Alan - I'm aware of clipping - notice that in the levels display (histogram), the input appears clipped, but the output level below shows a lower than max value, in fact lower than the input level. This is normal for this software, I don't know why it isn't more logical. But the software also has a nice local value display (not seen in my screen cap), showing the level of any location where the curser is hovered. So the highest value can be verified. The high point you see is actually outputting at much below 255.
About curve adjustments, I was advised by a friend, quite knowledgeable and experienced in scanning that if you prioritize some parts of the scale for optimum separation, best to place these in a straight, or steep part of the curve for scanning. To your point, you can't improve on some kinds of gradation after scanning, as scanning data comes from a continuous tone original. Photoshop is working with an already digitized (stepped) image. Or put another way, if you need a portion of the tonal curve articulated, and you increase it too much post scanning, posterizing can result. I used to see this in the early days of computer graphics in the printing business.
I'd like other opinions about this, I may be out of date.