Every scene is different, and you might change your mind about 'what is most important in the scene?'.
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Photo 1 was metered with a spotmeter on the 18% gray card, because 'correct exposure' of the gray card was the most important thing to get...the gray card is reproduced as a midtone.
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Photo 2 was metered with evaluative metering becajse the blue sky and the clouds was an important element, and 'correct exposure' of the gray card was not essential.
Gray cards are just references, 18% gray card is what supposedly chose Ansel Adam as a reference of mid gray for the zone system and what reflected meters are usually calibrated with. In the above scene, the first picture is "correctly exposed" (= to get a mid gray) for the dark part by the reflected spot or center weight meter. If your point of interest is in the sky, the gray card should be outside in the highlight area, something that it is not possible to do in many ocassions. So the use of gray cards have a very limited utility.
Matrix or evaluative metering is reading the brightness of many areas of the whole scene and checks for the differences. Then it chooses the exposure trying to preserve as much as possible shadow and highlight detail according to the recording media (negative/slide, CCD/CMOS sensor). Here a gray card adds nothing to exposure calculation.
There was a tendency in film evaluative metering to preserve highlights in detriment of shadows because of slide film. Modern evaluative metering also takes into account the actual color, so brightness is evaluated as RGB and not as a gray value (like reflected by a gray card), and the focus point to deduct where the photographers point of interest is.
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