Hey y'all,
I figured I'd post a big roundup of just random things I've changed in my workflow. I've been machinegunning out plates recently getting ready for a big trip, and I've been some pretty nice improvements to the process. I'll often post musings when I share pictures on Instagram, but those are near impossible to search for if you're looking for information, so I figured I'd compile the big ones here.
Masking the edges
I used to take 1/4" tape and mask the edges of each plate before coating the 1st Varnish. I was concerned that water would leak into the starch layer through the edges, and providing an area of contact between the glass and second varnish would neatly envelope the starch. In reality, the Lumiere second varnish has poor adhesion to glass, so the plate was much more likely to flake up at the edges and leak water in. Nowadays I just coat the whole plate with 1st varnish, starch, and 2nd varnish, and they perform much better (and are easier to coat!). The outer 1/8" or so says unflattened, because the roller wheel can't quite make it to the edges of the plate without bumping into the sides of the slot the plates go into.
Lampblack Heating
I noticed recently that I was leaving "fingermarks" when brushing in the lampblack into the plate - the areas near where my fingers were holding the plate had almost no lampblack deposited on the grains, while the cooler areas were considerably "dirtier" looking.
I've started preheating each plate to about 40C before brushing the lampblack now, and the results have improved considerably. This serves a dual purpose too - heating the plate causes the 1st varnish to expand, so cracks in between the starch grains appear. Brushing in the lampblack pre-emptively fills these in, reducing gaps that would often appear on the plate post-second varnishing.
I have absolutely no explanation on the mechanism behind the starch grains being "cleaner" when the plate is heated up.
Second Varnish Formulation
Using the Lumière 2nd Varnish has always caused artefacting - I can't be sure what it is, but it looks like the the Second Varnish warps slightly and lifts the starch away from the glass. In the vast majority if cases it's minor, and doesn't affect exposure or viewing. In extreme cases it causes cracking and delamination. Nearly all my original autochromes do not have this artefact though, so it bothers me.
I tried different formulations for the Second Varnish:
1.5x damar - this seemed to perform the best. Though it didn't eliminate the artefacting in all plates, it did reduce the severity in most cases.
1.5x nitrocellulose - no change from the standard formulation. Tended to have more gaps in the plate after drying.
3x (accidentally ended up being 4x) castor oil - Did not prevent artefacting. Emulsion adhesion was poor, but I probably should have washed the plates with soap and water before coating. Will need to try again after washing.
Second Varnish "Cooldown" Method
The plates must be warmed when applying the second varnish, otherwise the volatile ethyl acetate will evaporate and cool the plate down, condensing moisture into the starch causing cracks in the second varnish, and a "mother of pearl" sheen that reduces transparency. Keeping the plate warm and baking all the solvent off causes gaps/cracks to be "baked in", permanently leaving the gaps in place.
For a while I added a small quantity of "butyl-cellosolve" (5-10% volume) to the second varnish. It's a nitrocellulose solvent that is considerably less volatile. After most of the ethyl acetate had evaporated, the plate would gas out for the next 24 hours or so and the cracks would slowly close up. I theorize though, this exacerbates the previously mentioned "artefacting".
Now, I omit the butyl-cellosolve, and use the following method - I first heat the plates up to 40C, apply the lampblack, and then dose 10mL of varnish (diluted to 0.4g/10mL) to the plate. I then continue heating for an additional 2 minutes, before cutting power to the heating pad. This keeps the plate just warm enough initially, that the ethyl acetate rapidly cools it down to near-room temperature. This avoids the plate being too cold and pulling in moisture, but also from being too warm, and baking in the gaps. I should note that I use 1/4" glass as a leveling table retains the heating pad.
Coating
Since the emulsion has such high even-ness requirements, coating has always been a major PITA. I built a machine out of a 6040 CNC that can coat 14 4x5s at a time. The head's coating length is 5 inches, so that it'll work for 5x7 format too, though I have yet to try it. I'm still working some of the kinks out in the process, but the evenness of the coatings has been so great that I've hardly even thought about it since then.
You can read more about it in this thread:
https://www.photrio.com/forum/threads/making-a-glass-plate-coating-machine.176482/#post-2691986
I'd like to make a dedicated video on the various pieces of equipment I've built for the darkroom, and no doubt the story behind this will take up most of that.
I dilute my stock emulsion 1:2, and adjust the gelatin for a final 3.5% by weight, and coat 5mL per 4x5.
The Safelight Saga
I realized recently that my safelights weren't exactly so safe, and were in fact giving off tiny amounts of green light. I've had these lights for a few years now, and probably fogged any emulsion I made that was remotely fast. Now my exposures are pushing 2-10 seconds, instead of 2 minutes.
You can read a little more about that here:
Hi! I would really like to attempt to make an ammonia digest emulsion and would like to know if anyone here has any experience doing so. I've become pretty decent at making regular emulsions with dyes and sensitisers and would like to take the next step. Any assistance would be much appreciated! N.N
www.photrio.com
UV Filtration
I've been struggling for weeks trying to figure out why my fine-grained plates look so washed and lacked saturation. I finally had a breakthrough yesterday - As soon as I shot a test with a UV filter from a Cibrachrome printing kit, the colors absolutely popped. It appears enough UV was leaking through the grains, muddying the colors and reducing saturation. I figured the plates had enough protection from UV, between being shot glass-side first, as well as with a modern lens with a UV coating, but this apparently wasn't the case.
To Do
Now that I have extra plates that I can kind of just play around with, I'd like to start experimenting with using permanganate bleach instead of dichromate. Not just for my European bros out there who want to buy plates from me eventually, but simply for the fact that I'm working with the stuff on a daily basis. I'm incredibly strict about my handling and disposing of the stuff, but working with the stuff almost daily just can't be good for me in the long run. I'll be looking into other bleaches as well and see what works best.
I've finished a script for a proper autochrome video guide - 32 pages of it! And I've started taking footage for it as well. I wouldn't expect it to be out for at least a few months, but I'm hoping to make it a winter project.