A "sharp" developer to use with rotary processing

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nworth

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Ok, I'll inquire, HC-110 has a LITTLE but of pyrocatechol in it, so I assume PYROCAT has a LOT of it?

What's the difference? Both are neuro-toxins correct? I'm trying to educate myself. If I'm wrong and asking, try not to bash me, just want to be well informed.

Thanks.

No, but both are quite toxic. Both are category 3 toxins for oral ingestion, but pyrogallol is a category 4 (harmful with very short exposures) for dermal and inhalation, while catechol is less toxic for these routes. The MSDS shows catechol as a category 2 health hazard and pyrogallol as category 3. Catechol occurs in nature from many sources at concentrations not much less than fully diluted developer. Pyrogallol is a neurotoxin, but catechol is not. Both are harmful, given sufficient doses, to the kidneys and liver. Catechol is a moderate carcinogen promoter, especially in the presence of Cu(II); pyrogallol is a mutagen. It takes a considerable chronic dosage in susceptible strains of laboratory animals for either of these effects to be noticeable statistically. Both have been used with reasonable care by photographers for over a century with no notable health effects.
 

removed account4

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Just because they designed it to be used a certain way doesn't mean you have to do so.

unless of course you use non RS in a rotary processor with sheet film
then chances are you will be outtaluck. :whistling:

i use things other than what they were designed for all the time,
unless i dont want the suggested contraindication.

seeing stone is processing sheet film , why suggest he use a developer well known
and documented to cause dichroic fog ( even by koduck)?
when the good folks at kodak told me to use it ( non rs ) it was a mistake, and after the fog was there
they said, " why did you use that version of tmax developer, it causes dichroic fog"
 
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StoneNYC

StoneNYC

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What happens when I try and mix powders... This is why I don't like them...

ImageUploadedByTapatalk1392150654.274326.jpg

Was trying to make a Tech Pan developer...

Ugh... Well, we'll see how it comes out...

Why then send chemicals in baggies is beyond me, stupidest thing I've ever seen...

That's Phenidone by the way...
 

Roger Cole

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unless of course you use non RS in a rotary processor with sheet film
then chances are you will be outtaluck. :whistling:

i use things other than what they were designed for all the time,
unless i dont want the suggested contraindication.

seeing stone is processing sheet film , why suggest he use a developer well known
and documented to cause dichroic fog ( even by koduck)?
when the good folks at kodak told me to use it ( non rs ) it was a mistake, and after the fog was there
they said, " why did you use that version of tmax developer, it causes dichroic fog"

I'm not suggesting he use it. I was passing on my experience with it as similar to his DD-X which he has and likes.

Since I have both I'm going to give non-RS in my Jobo with sheet film a test, just to see if I can duplicate this dichroic fog.


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Stone,

Have you ever heard of a beaker?
Link

They are great for mixing your chemicals in. I usually use a two liter beaker, unless I'm mixing a gallon kit, in which case I use a large stainless steel container. Haven't gotten around to getting a gallon sized beaker yet.



What happens when I try and mix powders... This is why I don't like them...

View attachment 82032

Was trying to make a Tech Pan developer...

Ugh... Well, we'll see how it comes out...

Why then send chemicals in baggies is beyond me, stupidest thing I've ever seen...

That's Phenidone by the way...
 

wildbill

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Stone,

Have you ever heard of a beaker?
Link

They are great for mixing your chemicals in. I usually use a two liter beaker, unless I'm mixing a gallon kit, in which case I use a large stainless steel container. Haven't gotten around to getting a gallon sized beaker yet.

you mean beaker?
 

Roger Cole

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And, nobody says you have to scratch mix powders anyway. Try some ID-11/D-76. Easy as pie.

This. And Xtol, which many here have recommended, is not much harder. It just comes in two packets. They are all pre-measured, just dump into a measured amount of water at specified temperature and stir.

Xtol does require a large mixing container and bottles to store the resulting 5 litres of liquid though so I can see how it isn't ideal for his circumstances. That's not because it's a powder though, but because it comes only in an inconveniently large size.

You can't have everything and no photo succeeds or fails because of presence or lack of edge effects. Get some HC-110 and start shooting. :wink:


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miha

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No need for a funnel, just roll a small sheet of paper in the shape of a funnel and throw it away after you are done (a common lab practice). An oil brush comes in handy too.
 

Truzi

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Stone, you likely have chemicals in the house that are dangerous, but since they are considered "common," no one worries (or takes proper precautions). I don't think some of the suggestions here are more likely to cause problems. Even if they are more toxic, you are probably going to be safer with them than you might with drain cleaners and such.
 

cliveh

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What is this thread about?
 

miha

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Btw, is the new Adox/Paterson developer recently rereleased suitable for rotary?
 
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StoneNYC

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Yeah I'd recommend not doing that with Pyro. Catechol is pretty nasty too because of its vapour pressure. You can smell it everywhere.

But really, this looks more like working too fast and not being careful rather than an inherent problem with powders. So I'm not buying this.

Slow down and be careful. Read some good sources on chemical mixing, and the specific MSDS and precautions to take when handling/working with certain particularly nasty compounds (strong acids/bases, PPD, Pyro, Catechol) and you'll be fine. And in most cases you can avoid those compounds anyway. I've used the little bags from Formulary from time to time. They're not ideal but I haven't had any serious problems.

And, nobody says you have to scratch mix powders anyway. Try some ID-11/D-76. Easy as pie.

I was by no means "rushing" and this is the aftermath of me trying to store the REST of the opens phenidone in something other than a baggie, so yes I should have used a small funnel which I will get in case I do this again.

The actual 1.5g part was relatively less messy, but still, I just find it much easier to pour liquid than mess with mixing powder.
 

eddie

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I know this is subjective, but looking for new developer options.

I don't know why this thread has over 200 submissions...

Stone likes DD-X, so he should use DD-X. He'll never understand the effect rotary processing has on his negatives until he can compare it to results he received prior to the change to rotary . All too often, he posts about changing multiple variables at once. To understand any changes, they must be made one at a time, and the testing time put in to accurately identify the changes.
 

removed account4

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I don't know why this thread has over 200 submissions...

Stone likes DD-X, so he should use DD-X. He'll never understand the effect rotary processing has on his negatives until he can compare it to results he received prior to the change to rotary . All too often, he posts about changing multiple variables at once. To understand any changes, they must be made one at a time, and the testing time put in to accurately identify the changes.

i dont know eddie ..
i think he should switch films, and camera formats as well as development chemicals and methods ..
why make things easy when they can be difficult
 
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StoneNYC

StoneNYC

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I don't know why this thread has over 200 submissions...

Stone likes DD-X, so he should use DD-X. He'll never understand the effect rotary processing has on his negatives until he can compare it to results he received prior to the change to rotary . All too often, he posts about changing multiple variables at once. To understand any changes, they must be made one at a time, and the testing time put in to accurately identify the changes.

I did compare them to the results I had prior to going Rotary, and they were different, the edges were very soft as it was too hard and sharp, that's why I'm asking this darn question in the first place
 

eddie

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I did compare them to the results I had prior to going Rotary, and they were different, the edges were very soft as it was too hard and sharp...

I don't understand what you mean by, " the edges were very soft as it was too hard and sharp". How can something be too soft because it's too sharp?
 
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