I really appreciate your response, koraks! I know I've strayed away from the original topic quite a bit, but I might be spamming the forum if I post all my questions at once! At least it's more relevant here! Any further questions about the "why" regarding the changes from EXR to Vision might be better sent to Kodak at this point than me guessing.
You got it!
What happens, simply put, is that the developer is oxidized as it reduces exposed silver halide into metallic silver. This oxidized developer molecule then binds itself to the dye couplers that are nearby. The dye couplers themselves are colorless, but once combined with the oxidized developer molecule, they form a colorful dye.
Awesome, thanks!
Yes, that's how I understand it as well. The exposed silver halide grains/crystals are still for the most part silver halide (AgBr, AgCl, AgI).
Ok, cool! That was a bit confusing because before I would see examples explaining it like there was an invisible shadow of all the activated silver where there will be image density upon development. It hides how density differences are captured.
On that note, I wonder what
would be a good metaphor or picture to use? Effectively, the relative densities in different parts of the final image make the most sense, since that's what it produces in the end, but that "information" is contained in the latent image by different,
far weaker relative densities of silver among mostly unreduced silver halide.
Y'know, I'm really starting to think photography was a miracle in the first place....
A rehalogenating bleach links the metallic silver back with a halogen (chloride, bromide, iodide; usually bromide in a color negative process), converting metallic silver into a silver salt.
"Back"? But the rehalogenating bleach brings those halogens with it, right? Because the fix washed the existing, undeveloped silver halides away.
A non-rehalogenating bleach also forms silver salts, but these are easily soluble in water and are thus carried away from the emulsion. Silver halides are insoluble for the most part, so they stay put.
That makes sense, the silver halides precipitate and get stuck in suspension the collodion/gelatin/etc.
Hm, that's got me thinking, in emulsion-making if the byproducts of forming the silver halide salts are very soluble nitrate salts; do emulsions
need to be cut (as in the traditional noodle + wash steps) or is that merely increasing surface area and it would work in other ways? I understand washing liquid gelatin or an uncut block of gelatin directly with water might not make sense, it'd probably take a while to get through a block and I'm not sure if the gelatin would just capture it or get diluted by it, but what about after coating? I guess it's just a bit of convenience that you wash the emulsion once and then the plates you coat are less... salty. But won't that get washed out immediately upon development?
Bleach is a bit of a confusing name, unless it means the strong oxidant aspect, cause the
dye couplers seem to survive that step...
Sorry for the cavalcade of follow-up questions!
That's also possible, but budgetary decidedly less attractive for most mortals - including me!
In the end, a bulk roll of 35mm also allows you to do quick iterations on small snippets of film. Just load a small section into a cassette and expose it in-camera, or tape it inside a sheet film holder for experiments with an enlarger etc. etc.
Hm, are you not personally concerned with doing any experiments with motion picture negative but developing in C41? Or do you have ECN2 chemicals? From what I've heard that's the only way to get the colors
actually correct and reap the benefits of the higher latitude because it's a lower-contrast developer.
Thank you again for your patience with all my questions!
