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Kentmere 400 pushed to 800 or 1600 with Rodinal

Interesting. I think I've always used Rodinal immediately after mixing.
 
With Rodinal, it seems highly prone to aerial oxidation at working strength.

Okay, but if that's the issue at hand here, I think the example posted by @Milpool above says enough. Yes, rodinal oxidizes readily, but it'll work fine for 1 hour at least, even at 1+100. So it's not as extreme as you make this out to be. Other developers can be more problematic in this regard; esp. staining developers like 510 pyro.
 

With some films, with enough solution volume - which does not equal all films. The test was also done to look into stand development - if you add enough agitation to resolve the major uneveness that @Milpool mentions, that will effectively aerate the developer too, unless you use nitrogen gas burst (I think some of the testing by others was done with regular agitation). A density/ time curve would demonstrate when diminishing returns rapidly set in, but would require much more extensive work.

I'd also add that the 30 min result is roughly equal to what Agfa (US) suggested would be the outcome of 20 mins with regular agitation, and that the average gradients and curve shapes tell a key story about something that can be achieved in much less time with Xtol and regular agitation (and the potential to land higher aim densities).
 
As to the agitation - sure, it would make a difference. The other points, I'm more skeptical about. There's not enough dissolved oxygen in any film to explain why rodinal at any sensible dilution would deplete after 30 minutes with one film but not another. The notion of curve shapes and gradients all nice and all, but not directly related to the question whether rodinal poops out after half an our.

I think @Milpool's test shows beyond any reasonable doubt that what you said earlier was exaggerated. There might (will) be diminishing returns, but that doesn't place them at firm zero after 30 minutes as you implied earlier.
 
There might (will) be diminishing returns, but that doesn't place them at firm zero after 30 minutes as you implied earlier.

Just curious. Has Agfa (or now Adox) made any official statement on the expected life of Rodinal working solution after it has been mixed from the concentrate?
 
Not really, and I wouldn't expect them to because it's kind of a vague situation where activity is in a grey area and drops off rapidly. Here's what they say in the datasheet for Rodinal/Adonal (which actually is an Agfa datasheet they still use):

This leaves an open question what constitutes "a short time".
 

I can say that I've been able to overdevelop a film with 510-pyro 1+300 stand development for one hour. That film was Delta 100. Frames became somewhat usable with DSLR digitization but were unusable out of an Epson with all adjustments off. I eventually stopped using 510-pyro at dilutions other than 1+100 because I found the times too unpredictable, unlike Rodinal where an hour seemed to do a decent job on just about everything. Maybe I needed to go to 1+500 to get the results I was looking for, but it definitely didn't strike me as a developer that tapered off.
 
My regular 35mm film is also Fomapan 100, because bought in bulk it's affordable on a tiny pension! I like it (but not more than FP4 that I shot in the 80's and also bought in bulk). When I have a camera with a working meter it's box speed, when not it's a guess or a toy camera without adjustment. It just works for me! I have one p&s camera that tends to favour slow speeds and in which I use K400 (DX coded and a metal cassette). In box cameras I like Fomapan 200 because it's just so flexible. Pity about the black spots that I can't get rid of with my scalpel without wrecking the print! I do not like Fomapan 400 because of the plastic cassette (light leaks straight out of the box and the cassettes won't even fit in some of my cameras). The alternative for me is K400 or Agfa APX400 which are reasonably close to Fomapan prices through internet suppliers in EU. If I used more 400ISO I would probably go to Fomapan to bulk load but I only have one loader and I prefer slower speeds. Gone are my days of Pan F and Tri-X developed in Perceptol - that's poverty (I think!)

I have recently taken to stand developing with Rodinal (not for everything but there is a convenience in being able to load the tank and leave it work while I do something else). 60 minutes development. I use a spacer to raise the reel which means that while my dilution is 1:100 (ok 1:99 really) I am using 8ml of developer for a 35mm film instead of 6ml (1:50) that I would use developing with agitation. The spacer means that I need 800ml of liquid to cover the reel (I think when I measured the volume for 35mm film it was less but 127 is about 800ml so I keep it the same for both). After reading this thread I ought to try a test at 30 minutes and a parallel one at 60 minutes to see if I can see a difference but it would only be by eye and subjective, I am not equipped for measuring densities! I use Rodinal for some cameras like p&s where it seems to suit and D-76 for the more serious stuff. If I wanted to push the developing it would be with D-76 but it's not really my style, I prefer to avoid it and just use slower speeds.
 

Good question for @ADOX Fotoimpex or Mirko to answer. Given that many users of Rodinal do stand or semi-stand development these days, a definitive answer would surely be helpful.
 
Without wanting to be facetious, what do you expect from this hypothetical answer - which I'm quite sure we will never receive? Given the nature of the developer, the manufacturer cannot be realistically expected to state on the record "it will last for x minutes/hours". It basically goes downhill from the moment of mixing, and the only honest answer how fast that goes is a firm and secure "well, it kind of depends..."
 
Oxidation issue aside, I can imagine people getting different sensitometry results due to temperature drifts / gradients etc. Since I was trying to get as close as I reasonably could to "stand" for some sort of baseline ideal I tried to control for these variables the best I could. I doubt people generally do that though, because the technique is often assumed not to require control.

In any case, my findings were that it doesn't seem to do what people think it does from a "macro"-sensitometry perspective. Even if you can tolerate the poor uniformity, I'm not sure what is to be gained. If the motivation is pushing, this does nothing special - it just increases the gradient. If the motivation is to have some sort of automatic process for all films etc., this doesn't give you that. If the motivation is enhanced edge effects, while my results are silent on that front there are better/easier/less problematic ways to get edge effects.

 
I actually have a quick question that just popped into my mind : is it possible, on the images of that roll of HP5 at 3200 in Rodinal that the grain appears not overwhelming (at least to my taste) because they were scanned on an Epson V600 ? Would that grain appear much more prominent if "digitized" with a DSLR and macro lens ??
 
Even modern film like HP5+ TriX, and even Kentmere are much more fine grained than films from the 70 and 60s, when pushed to 3200 a three stop push. I don't if the manner in which you scanned it made that much of difference.
 
The way the film is digitized does make a difference and a flatbed tend to smooth things out a bit.
 

The grain will be blurrier at a lower resolution. How contrasty the grain is largely depends on how much you or your scanner's software increased the contrast. Also, the last thing you want to do is use a sharpening radius setting that primarily sharpens the grain. I don't sharpen at all. These are Tri-X in HC-110.

Same film, same developer, same magnification -

DSLR



Epson

 
Even modern film like HP5+ TriX, and even Kentmere are much more fine grained than films from the 70 and 60s, when pushed to 3200 a three stop push. I don't if the manner in which you scanned it made that much of difference.

I'm not very well versed in how much films that have existed for a long time, like Tri-X or Ilford films, have evolved over time, but yes, they usually look less grainy to me than old photographs. I suppose I'll see for myself when I try to digitize them if it looks really different.
There is a channel on YT I just stumbled upon while looking at ways to push HP5 and their results. This guy ("Dan Mars, Photographer?" is the name of his channel) has pushed some films way beyond what I thought was possible, like FP4 @800 in Rodinal, and the results are honestly surprisingly good (at least, if you like that kind of look, which I completely understand if people don't). And he "scans" with a Leica SL2, so... Anyway.

The way the film is digitized does make a difference and a flatbed tend to smooth things out a bit.


Thank you for your answers !
I scanned them at 2400dpi (which, as far as I can tell, is the maximum realistic resolution of the V600). As for the contrast, I think I tried to make them quite flat (I don't remember exactly, that was like... in 2021, maybe). I don't remember either if the V600 does some sharpening or not. The results I've shared have not been sharpened in Lightroom, at all. And they looked like straight from the scanner.
 

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Are these still Kentmere 400 at 3200 in Rodinal at 1+50 for 30 mins? Whatever these are they look pretty good to me

pentaxuser
 
Are these still Kentmere 400 at 3200 in Rodinal at 1+50 for 30 mins? Whatever these are they look pretty good to me

pentaxuser

Ah, no, sorry ! They're the old HP5+ at 3200, Rodinal 1+50, 52 minutes.
 

It is hard to compare old prints with new scans, because of the differences in the films, differences in printing tastes, differences in enlargers - e.g. condenser light sources vs. diffused light sources - and differences in reproduction media - e.g. magazine pages vs, phone screens!
But yes, Tri-X in the 1970s was more grainy than it is now, and we used to print it or share it in ways that showed it clearly.
These pages are most of my 1970s 35mm black and white negatives and almost all of them are Tri-X:

 
Ah, no, sorry ! They're the old HP5+ at 3200, Rodinal 1+50, 52 minutes.

OK and thanks. For what it is worth I have an old Afga film development sheet and HP5+ is one of the films that is not recommended for Rodinal

Maybe Agfa were wrong?

pentaxuser
 

Wow, Matt even the inside covers of the album look grainy

pentxuser
 

That is a lot of Tri-X indeed
I really do like the look of Tri-X, generally. It's just the price that is a bit steep for me... but the quality is absolutely there, no doubt.

OK and thanks. For what it is worth I have an old Afga film development sheet and HP5+ is one of the films that is not recommended for Rodinal

Maybe Agfa were wrong?

I think many people consider Rodinal inadequate (to say the least) for higher speed films, and I can understand why. I am very, very inexperienced in home development, so I cannot say if there are ways to mitigate the "impact" of Rodinal (like maybe more gentle agitations ?), but the few rolls I've developped myself (HP5 at 3200, Kentmere 100 and 400 at box speed) turned out fine for my taste. Again, that is a very personal taste, and I also love how clean finer grain films look in some cases.
I've seen much cleaner results, especially for pushing, with Xtol for ex (or DD-X), but I have no idea whether or not those were exposed for the shadows or highlights. And Xtol, apparently, needs to be kept in full bottles, and I'd rather stick to something that is ultra simple, considering how little experience I have.
Anyway. That's a lot of unanswered questions I'll try to do the Kentmere 400 @1600 test in the coming weeks, and I'll post some results here. It will probably be on 120 film though, because doing 36 shots that might turn out meh would be quite disappointing (and take longer) compared to only 12 ^^.
 
Wow, Matt even the inside covers of the album look grainy

pentxuser

Pebbly I say, Pebbly.
Of course, that binder is the same vintage as the negatives about 50 years old!
I should scan some of those, and print them again too.