Feel free to let others respond.
Certainly so. That's the implied nature of a forum. Anyone can chime in.
And not excluding that possibility, I'll try to explain why I believe your question about 99.99% of the colors being mixes of primaries is not a promising avenue in the context of this thread.
Firstly, physics doesn't care about primaries. As
@Mr Bill above explains (the Feynman lecture), there's no natural/biological given of a 'primary' color in human vision. It turns out there's no such thing in outside the biological realm, either. Any selection of colors that we call 'primaries' is a human construct, and nothing more.
This becomes especially apparent if you realize how colors are rendered in real life, especially in reflectance: they are are in virtually all cases broad reflectance spectra that reflect a mass of wavelengths at various efficiencies. Not only does that relate in no way to whatever primaries you could think of, it doesn't even involve any particular colors being reflected. The best characterization is 'a whole bunch of them'.
How large a bunch? Well, this leads me to the second reason why your question doesn't make sense to me. You asked if it's not true that colors are generally mixes of primaries instead of pure colors. Let's look at those pure colors for a minute, particularly on a spectrum. The rainbow is a good example. How many colors does it have? I'll save you the time of counting - it's infinite. It's a continuum, after all (there's some lumpiness due to emission spectra of the sun and blockage by the atmosphere, but it's still pretty continuous).
So there's an infinite number of colors that are constructed as a single wavelength. This means that the question "aren't there more colors that are mixed colors than distinct wavelengths" mathematically works out to "isn't there some number that's larger than infinity". If you want to work that one out, I can probably give you the number of a decent science faculty where you'll find many people better versed than me on this cross-section of science and philosophy. Don't count on any practically relevant conclusions.
There are some caveats; for instance, digital displays (and, coincidentally, pointillist paintings, or halftone screen printed media) do construct colors by combining a distinct set of primaries at various intensities or reflectance levels. However, this is of course just an optical illusion and the millions of colors constructed this way aren't real - they're the figment of our imagination that you alluded to earlier. But this is firmly limited to the domain of hues constructed by adjacent, distinct colors that blend into each other due to the limitations of human vision.
In conclusion, if you think your question through, you end up with the realization that (1) primary colors aren't very relevant in terms of understanding how color emerges, nor in how we perceive it and (2) that the story about reflectance spectra as ways in which color emerges is actually something I already mentioned (and illustrated) on page 1 of this thread. So one angle is a dead-end street that at best draws one into a swamp of semantics, and the other is a rehash of material that's already presented and there for the picking up.
Hope that helps.