There is definitely a bit of variation at higher latitudes because the light has to travel through more atmosphere, and there are of course effects from haze and pollution. The spectrum of course changes because of the atmospheric differences too - in Australia we have far more UV than Europe due to the antarctic ozone hole.
I recommend having a look at
some of these surveys and their techniques and
some of these insolation maps. The latter are derived for the purpose of budgeting PV solar cell outputs and therefore include annualised weather patterns (cloud etc) so you should ignore the variations wrt sea/land and longitude. However, they do show a strong and uniform variation in insolation with latitude. Some of the papers show the variation throughout the day, and on a clear day, you can expect about 15-20% difference between mid-morning and noon, depending on your latitude, which is about EV0.3 difference.
I get EV14.8 in Adelaide in mid-summer, and about EV14.3 in winter. When I travelled Europe (Prague, St Petersburg) in late summer, it was more like EV13.8. I'd be interested to see a reading from inside a polar circle.
PS Sunny 16 is EV 14.66 not 15. EV15 would imply f/16 1/125 @ EI100.