One could simply find a plain, uniformly illuminated wall, and point the prospecitve spotmeter at it, and immediately do the same with your dSLR...both should yield similar readings even though the coverage angle are different.
I've done this before. Its frustrating because you soon discover that, even if it looks uniformly lit to your eyes, the wall often isn't uniformly lit in reality.
I've also tried measuring off gray cards, only to discover that not all gray cards are identical and there can be a 1/3 stop difference from one to the next.
What I really want, is some "gold standard reference" light source that I can use for any and all meter calibration purposes.
For incident readings, a voltage stabilized enlarger lamp actually does a pretty good job here. I'm tempted to toss a gray card on the baseboard and see if the same can give good results for spot meters.
(Though this will still all be at a lower light level than typical outdoors.
The other problem I've run into, especially with older meters, is that error may not be consistent across the full range. Just because it gives the right result in dim lighting doesn't mean it'll give the right result in bright lighting (or vice versa).