I recently bought the illustrated bottle of 20+ years old Rodinal. I get the age from it coming with an instruction sheet listing times for Panatomic-X and Ilford PanF (not the Plus version). The contents were measured as 500ml, equal to that specified on the container, so it was probably unused.A film was developed in it diluted 1:50, it works like new.The graduated cylinder contains Rodinal concentrate from the Agfa container.
From the pic, the color is still light for Rodinal, showing that after 20+ years it has hardly oxidized.
Seems the manufacturers plastic bottles do a good job in keeping out air and preventing oxidation, at least in this case.
View attachment 174712