I'm not sure if I see what you mean. What I see in the snippet of the argyrotype included in your post is a severe compression of the highlights and upper midtones and possibly fogging, so it basically all bunches together into unseparated tonality. The background of the branches against the sky shows very distinct separation in your digital version, but on the actual print, it's all very closely spaced tones.For some unknown reason the mossy branches are blown out and the sky is where it should be when the Argyrotype is printed.
I'm not sure if I see what you mean. What I see in the snippet of the argyrotype included in your post is a severe compression of the highlights and upper midtones and possibly fogging, so it basically all bunches together into unseparated tonality. The background of the branches against the sky shows very distinct separation in your digital version, but on the actual print, it's all very closely spaced tones.
I would expect the main issue is either in the printing process, which may not yield good highlight separation due to fogging (e.g. parts of the sensitizer not washing out well), and/or problems with the adjustment curve (i.e. not linearized well for this paper/process combination).
PS: I've taken the liberty to include something about the lack of separation of highlight tones in the title of your thread.
Perhaps this is some kind of proximity effect - i.e. bleeding of the surrounding darker areas into the highlights. I have seen it happening in cyanotypes. Not sure if that is a thing in kallitype or not, but presumably during development, some of the Fe(2)'s flow over to the neighboring bright areas where there is much less or none and create greater density than expected. When the densities are relatively similar, the effect is not as pronounced such as in the case of mossy branches, Step tablet wouldn't show this if the blocks are large enough and you are measuring the middle portion.
:Niranjan.
3) +50 yellow, moss RGB 198, almost Zone VIII, moss has texture
Ok, so the problem is you're blowing out the highlights on the moss. The correction you apply is too drastic. This is largely due to the extreme adjustment curve you appear to be using for your argyrotypes. In your place, I'd go back to the linearization process and re-do that from the start. The snippets with the adjustment curves applied to them show a dramatically reduced tonal scale which is likely to get you into trouble at some stage, and posterization and loss of highlights or shadows are only to be expected.
The root cause of this IMO is to be found in the print settings you're using for the negatives. Are you using QTR or the Epson drivers (I vaguely recall you use an Epson printer...)?
I'm not suggesting otherwise.The problem is occurring before the negative is even made.
I'm not suggesting otherwise.
I think the main problem is the fact that at some stage in the process, you need a curve adjustment that basically smashes most of the tonal scale together in a relatively small part of the tonal scale. This exacerbates any potential issues with stacked adjustments also if these precede the final adjustment curve.
I can't tell for sure what's happening in your workflow since I don't use Capture One, and all I have here is 8-bit renditions of your images. I assume/hope you're doing all these edits in a higher bit depth, otherwise it's a sure-fire path towards failure to begin with. At the end of the line, things will likely get smashed flat into 8 bits at the printer driver stage, but that's basically a black box. I'd ensure that everything up to that point is 16 bit.
You may be able to get things to work even with this extreme curve, but you'd still be running a large risk of poor tonality at the upper part of the curve due to posterization. If you take a look at the histogram of your example #4, you'll notice that a significant part of the image data is lopped off and that evidently wasn't the case in #3.
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