A chain is 66 feet. There are 20 chains in a furlong, 80 chains in a mile. 10 chains to the furlong (1/8th of a mile). 200 metres to the furlong, making five furlongs pretty close to a kilometre.
A chain is close enough to 20 metres, A rod is 16 1/2 feet, close enough to 5 metres.
There is no practical conversion for a league, since it is the distance and average man can walk in an hour (3.5 miles or 5.5 kilometres - which shows up another advantage of metric being that you can walk a lot faster post metric)

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My point being that these metric distances are easily transferable to the "useful" everyday category
Imperial units are an anachronism and obsolescent. Except on golf, as I may have mentioned.