Flexicolor Reference: b-2020-c41.pdf

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Bormental

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Having gone through all Flexicolor-related publications by Kodak and going through endless threads here on Photrio, I was taking notes. In the end, I compiled a small document for my own reference, which I am attaching.

I have 3 goals here, the last one is obviously self-serving
  • Make it easier for future newbies to find information.
  • Have a lightweight and up to date replacement for z131 and cis49
  • Error checking, I will update and re-upload the PDF if you guys spot any errors
What's inside:
  • Development times
  • CAT numbers
  • Fixing 1L
  • Replenishment rates
  • Chemical expiration information (community advice)
 

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Rudeofus

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Very nice list! One thing, which is unclear to me, is the table listing very low capacity for these chems: 3 rolls of 120 film per liter of color developer sounds very low. Does this mean "in case of no replenishment" ?
 

Mick Fagan

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I too seem to think your film area development per litre is incorrect, although I am ready to be corrected.

For the last 35+ years, I have been processing C41 film using 8 rolls of 135 or 4 sheets of 4x5" or 1 sheet of 8x10" film(s) for every litre of full strength C41 developer. Have things changed, or have I been doing it incorrectly?

Mick.
 

Mr Bill

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Very nice list! One thing, which is unclear tkod me, is the table listing very low capacity for these chems: 3 rolls of 120 film per liter of color developer sounds very low. Does this mean "in case of no replenishment" ?

Yes, that number is given in Kodak's Z131 manual; it's in the first part of table 3-3, "Capacity of Unreplenished Solutions - Batch Processing."

It seems like many of the aftermarket chemical makers suggest substantially more capacity, though. In my considerable experience with Kodak materials and literature they have tended to be fairly conservative in their recommendations. But the reality is that this depends very greatly on the exact makeup of the images; heavily exposed film will exhaust the developer faster, whereas mostly clear film will barely affect the developer strength.
 
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Bormental

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Very nice list! One thing, which is unclear to me, is the table listing very low capacity for these chems: 3 rolls of 120 film per liter of color developer sounds very low. Does this mean "in case of no replenishment" ?

The numbers are official Kodak guidance taken from Z-131. Yes, that's assuming no replenishment. @Mick Fagan there are substantial differences between Kodak's official recommendations, that tend to be conservative, and community wisdom. I have assembled only the manufacturer's data there. One area where I made an exception was "Chemical Storage Life" table.
 

AgX

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3x 120 or 1.5x 135 already would mean 670ml necessary per 1x 135.
That again is 2.7x what is used in a standard inversion tank, or 4.8x what is used in a standard rotary tank.

Or with other words: already without replenishing after a run such processing would go far beyond the capacity limits for the developer bath. According to Kodak.


EDIT: got figures wrong , Kodak's capacity limit is twice as high than I put it. (see post #12)
 
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Bormental

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@AgX sorry, not following. What changes are you proposing I should make?
 

koraks

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I think the point he's trying to make is that if the Kodak datasheet was correct, rotary processing a single 135/36 roll in e.g. a Jobo 1510 (~150ml) wouldn't work properly. Which it does, implying that the Kodak datasheet must indeed be very conservative.
 
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Bormental

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I see. My understanding is that a solution capacity and minimal required volume are related, but one should not be derived from another. The minimal amount of a developer may indeed be ~150ml*, but this does not mean you can divide 1L by 150 to arrive at 6-roll capacity, because if you develop them sequentially and pour the used developer back into the 1L bottle after each roll, the development time may need to be raised after the 4th roll. My understanding of Z131 "capacity" table is that it allows you to process N rolls of film using 1L of a solution without having to increase the development time. Happy to be corrected.

* I do not know what it is, just using an example from above.
 
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reddesert

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3x 120 or 1.5x 135 already would mean 670ml necessary per 1x 135.
That again is 2.7x what is used in a standard inversion tank, or 4.8x what is used in a standard rotary tank.

Or with other words: already without replenishing after a run such processing would go far beyond the capacity limits for the developer bath. According to Kodak.

The document and Table 3-3 of Kodak's Z131 say: 3 x 120 rolls, or 4 x 135-36 rolls, per liter.
Not 1.5 x 135-36 rolls.
 

AgX

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Sorry, You are right, I made a mistake (going on Apug, whilst doing other work...)
I took 2x 120 = 1X 135, whereas it is more likely 1x 120 = 1x 135,

But still this means, that Kodak advise is more conservative than practice shows to work, especially in rotary processing.
 
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AgX

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And as I recently put it in another thread, there still should be made a test in amateur processing with in parallel processing film in the very minumum volume as in rotary processing and and in a surplus bath with about 3x that volume and a critical examination.

But at least the people doing semi professional Jobo processing with test strips etc. come near or reach the industry standard.
 

halfaman

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I am bit confused. Process times are for rotary tube but there is also a replenishment table. Kodak gives no replenishment rate for rotary tube processors because all solutions must be discarded after a single use with the exception of the bleach that can be reused up to the full capacity (page 3-6 of Z-131 document).

Where is the replenishment rate coming from?
 
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Bormental

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Replenishment rates come from sink-line processing, Table 3-2 from Z131. Yes, Kodak does not recommend replenishment for rotary tube (because of small amounts of developer involved) but as I said, the document is a combination of Kodak instructions and community advice. Multiple people have reported success using two available developer-replenishers in replenishment regime using the rates above with Paterson tanks.
 

Mick Fagan

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The numbers are official Kodak guidance taken from Z-131. Yes, that's assuming no replenishment. @Mick Fagan there are substantial differences between Kodak's official recommendations, that tend to be conservative, and community wisdom. I have assembled only the manufacturer's data there. One area where I made an exception was "Chemical Storage Life" table.


Hmm, I can see a difference as my publication (hard copy) is a March 1975 C41 process Z-121 with a supplementary Z-121A Special Instructions for Using Rotary Tube Processing for Process C41.

In late 1975 I was introduced to the C41 process along with a couple of other work colleagues by Kodak Australia. This was mainly for continuous replenishment deep tank Dip N Dunk machines, but we had another system for backup for when the processor went down or off.

We had multiple power failures back then and the diesel generator on the roof revved up and down like a yoyo as big gallery camera lights went on and off with their 8000W of lights thereby changing the frequency of the power and upsetting the processing machine timing. C41 being the shortest process time of commercial development, outside of Lithographic B&W film, was greatly affected by power frequency changes which altered the electrical motor speeds of the machine. In those times for important work, we batch processed by hand in tubes; that was the theory, the practical was slightly different.

As mentioned by you we needed to use straight chemistry, not replenished, for the rotary processing. Another aspect was to ensure that the C41 developer was mixed with 4.8g of CD4, not 4.5g of CD4 per litre. We initially had problems as the Americans out here were using gallons, which is fine, except the USA gallon is smaller than the Australian gallon. They switched over to metric once we found the problem, then we did tests using control strips to get working square mm per litre film developing answers.

The answer, after looking up my notes scribbled in the margins of my Z-121A special Instructions Sheet, was 250ml of developer for each 8x10” sheet of film; which equates to 4 rolls of 36 frame 135 film. I have used that number of film area ever since. However, I will concede that for quite some years I mixed up C41 developer from scratch with 4.5g per litre of CD4. It would appear that I have been incorrect for around 30 odd years of C41 film development by doing 8 rolls for every litre of developer. But as has been noted, the conservative nature of Kodak with their chemistry suggestions, seems to have saved my bacon.

Somewhere along the line and after I purchased a Jobo CPE2 rotary processor with lift, I started developing C41 at home, this was in the 80's. Now with the 1540 tank, one could process 4 rolls of 135 film with 500ml of developer in a one shot process. It must have been then that I somehow switched to 8 rolls of 135 film per litre. Initially I was able to process control strips kept with dry ice at home, then take the developed control strip to work the next day and do a reading. I had perfect control strips, in fact, my control strips were better than the big processor we had at work. This boiled down to the big processor worked on replenishment and could literally have 30 8x10" sheets go through, then almost nothing for the next 3 hours as lunch and new set-ups happened, followed by a flurry in the afternoon as the next big load of 8x10" film came through. It was a daily battle to keep the developer baths online, something I didn't have with one shot development.

I also note that I got my film numbers completely wrong when I quoted from memory; I 'll blame it on advancing age. :smile:

Mick.
 

halfaman

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Replenishment rates come from sink-line processing, Table 3-2 from Z131. Yes, Kodak does not recommend replenishment for rotary tube (because of small amounts of developer involved) but as I said, the document is a combination of Kodak instructions and community advice. Multiple people have reported success using two available developer-replenishers in replenishment regime using the rates above with Paterson tanks.

Ok, clear. I think it will be nice to identify in the document the source of each table as a footnote or similar for maximum clarity. In the case of replenishment I would put a note that Kodak does not reccomend it, so it is up to the reader to follow it or not.
 

Mr Bill

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I think the point he's trying to make is that if the Kodak datasheet was correct, rotary processing a single 135/36 roll in e.g. a Jobo 1510 (~150ml) wouldn't work properly. Which it does, implying that the Kodak datasheet must indeed be very conservative.

To be honest, I'm pretty doubtful that it's really in spec. Working adequately? Probably yes, more or less. People who use one of these machines, if they test via control strips, may well be tweaking the temperature to get control strips into spec. But this doesn't necessarily mean that the chemicals are in spec with the normal reserve capacity.

What's my basis for saying this? Well, I've spent a lot of years working in high-volume processing with routine chemical analysis for troubleshooting, so working with such things is sort of routine. It looks like the main restrainer, bromide ion, can easily go significantly over spec. Like so, for the technically inclined:
From published info we can see that the NaBr in developer should run about 1.3 g/l (Haist published the C42 formula). Next, from the Z131 manual, we can see that the aim LORR developer replenishment rate is about 25 ml per "roll" (spec says 5 ml/ft for 35mm perf film; x 5 ft = 25 ml). So we presume that the roll of film, bringing the 25 ml of replenisher to NaBr spec, supplies ~ 0.032 grams NaBr. But... in the Jobo, with no replenishment, it increases the NaBr concentration to about 17% above spec. So, the development starts out with the main restrainer at spec level, but by the end of development it is roughly 15 to 20% high. Now, since bromide is released in proportion to silver developed, one might presume that CD-4 is similarly depleted.

I should emphasize that the above is theoretical at this point - it has not been verified by chemical analysis. But I'd probably bet a lot of money that it's pretty close (I'd recheck the numbers pretty carefully before putting a lot of $$ on the line).

Now, anyone who has run replenished systems knows that changes in rates are typically made in 10% increments. For example, if a process is getting near the lower control limits a 10% replenisher rate boost will bring it back near center. So while ~10% error is more or less ok, double that is getting pretty bad. So the 15 to 20% NaBr increase over aim spec (at the finish of processing) is quite a lot. But as long as one doesn't reuse it, the results presumably are pretty decent.

Now, I mentioned a "reserve capacity" for developer. I've mentioned before about testing we (where I used to work) did on, for example, Portra 160 in our portrait studio chain. We could overexpose by perhaps 4 full f-stops, and when hand-balanced optical prints were compared to the "normal" exposure, the color was near a dead match. This is not a casual statement - I mean that professional color correctors, working in a specially-lit color booth essentially cannot tell them apart. Fwiw the film processing was done in cine processors with large tanks so even a lot of heavily exposed rolls would not put even a "blip" on our control charts. But if you tried even a single roll using only 150 ml of developer, you'd probably come to the conclusion that Portra 160 can't handle overexposure. Which would be completely erroneous.

Anyway, so much for such a system working "properly," or whatever one wants to call it. Maybe this helps explain why Kodak may take such a conservative position.

By the way, the commercial processing standard is to use replenished systems (you can't do this with color developers in a Jobo, as the aeration will tend to "kill" the developer). In our cine machines running LORR developer replenishment (around 25 ml/"roll") we could process about 35 to 40 "standard rolls" per liter with NO DEGRADATION of the developer - it always remains chemically in spec. As opposed to the 3 rolls/liter unreplenished per Kodak, or 6 to 7 rolls per liter using 150 ml developer batches, where the developer has become seriously compromised, chemically, after a single run. I don't know if this bears repeating, but I'll restate it: the LORR replenished system can stretch the developer capacity to about 6 to 12 times more film than the non-replenished systems being discussed, and the developer remains in spec the entire time.
 

Tom Kershaw

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By the way, the commercial processing standard is to use replenished systems (you can't do this with color developers in a Jobo, as the aeration will tend to "kill" the developer). In our cine machines running LORR developer replenishment (around 25 ml/"roll") we could process about 35 to 40 "standard rolls" per liter with NO DEGRADATION of the developer - it always remains chemically in spec. As opposed to the 3 rolls/liter unreplenished per Kodak, or 6 to 7 rolls per liter using 150 ml developer batches, where the developer has become seriously compromised, chemically, after a single run. I don't know if this bears repeating, but I'll restate it: the LORR replenished system can stretch the developer capacity to about 6 to 12 times more film than the non-replenished systems being discussed, and the developer remains in spec the entire time.

From my experiments with replenishment of the Flexicolor developer in a Jobo processor (1000ml working solution) - I would highly recommend sticking more closely to a suggested capacity of 3/4 films per litre, and forget about replenishment - the process seems to work fine initially but then colour quality and evenness disintegrates - density looks okay from casual observation of the negatives, which could lead a photographer into trouble if processing a batch of film before checking for consistency of results via optical printing or scanning.
 

Mr Bill

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From my experiments with replenishment of the Flexicolor developer in a Jobo processor (1000ml working solution) - I would highly recommend sticking more closely to a suggested capacity of 3/4 films per litre, and forget about replenishment - the process seems to work fine initially but then colour quality and evenness disintegrates...

Yes, I read your post about it, and I think it was a well-handled and useful test for anyone considering such a thing.
 

Mr Bill

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And as I recently put it in another thread, there still should be made a test in amateur processing with in parallel processing film in the very minumum volume as in rotary processing and and in a surplus bath with about 3x that volume and a critical examination.

Yes, but a more revealing test would probably be to take the developer, at the completion of development, and use it to develop only a "process control strip" (or other small test strip). A lot of people would probably be surprised at how "bad" the developer has become by the end of the processing run.

Or another revealing test would be to process some overexposed film. This is not so farfetched as many people seem to like derating their color neg film by an f-stop or so.

Of course it is important to control what's in the test scenes - low key portraits would put only a small stress on the developer, whereas high key or snow scenes, etc., will degrade it much faster.

At any rate, the ability to scan film gives the ability to more or less correct just about any deficiency. Whereas in optical printing, which is what I grew up with, film developing deficiencies can be a big problem. The outfit where I spent so much time specialized in (high-volume) portraits, which I consider to be one of the most demanding tests of the negative/paper system; people run the gamut from very dark to very pale complexions, and have a variety of hair colors. To print all of these with pleasing color reproduction doesn't allow much leeway for processing error.
 

koraks

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Working adequately? Probably yes, more or less.
That's the only thing I can tell from my own experience and I think it's similar for most Jobo users. Which means you may very well be (and probably are) correct about the used developer being out of spec in terms of halide content and possibly developer oxidation. The difference here, I think, boils down to if "adequate" is good enough, or "exactly in spec" is required.
Personally I use it one shot and don't systematically overexpose by more than 1 or maybe 2 stops. I also notice no difference between short lengths of film (eg 12 exp) and longer lengths (36) developed in the same (one shot) volume. So for me, that's adequate.
 

AgX

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Yes, but a more revealing test would probably be to take the developer, at the completion of development, and use it to develop only a "process control strip" (or other small test strip). A lot of people would probably be surprised at how "bad" the developer has become by the end of the processing run.

A bath not proccesing adequately in its is second run not necessarily must have been too bad for yielding in first run results up to standards.
Or do you see that differently?
 

Mr Bill

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A bath not proccesing adequately in its is second run not necessarily must have been too bad for yielding in first run results up to standards.
Or do you see that differently?

Yeah, I do see it differently. But keep in mind that I have not actually done the test with developer changing significantly during the process run, so I am guessing at the result.

Here comes one of my long, tedious posts:

I see the developer as going from "good" (ideal) at the beginning of the process run, to substantially deficient at the tail end of the run. So that the actual result is sort of an average of the entire changing process. And I understand that a lot of people will be happy to simply look at that final result, then decide if they are satisfied with it or not. My view on this is that there is nothing to compare it against, so it is easy to be satisfied. But SHOULD one be satisfied? (I'll put some actual experience in the last paragraph.)

So to decide if the "averaging" of the developer condition is "good" (or not), I think that one needs a comparison. It could be either the beginning of the cycle (completely good developer) or at the tail end of the cycle (degraded developer). I just picked the tail end, as I think the result would be more obvious on a control strip, and thus be more eye-opening to someone. From there I think they are in a better position to decide if they want to investigate further or not. Let me demonstrate with an example of personal computers: imagine that you were still using your prior version, and had never seen anyone faster. If someone were to ask, "are you completely happy with it" I'm guessing that you probably would be. But... if you had the opportunity to compare to a more modern one... suddenly the old one is perhaps intolerable. But without a comparison, everything seems perfectly acceptable.

Now, the photo experience I mentioned... let me say that my employer was a studio chain in the us - literally thousands of studios, and every hair color and complexion that exists in the US had probably made it into our studios. (The chain no longer exists, went "belly up" within about a year of Kodak's bankruptcy) But we did portraits, and tested pretty extensively to find "good enough" materials - films and papers. These were always the professional portrait/wedding films, and matching professional papers of the day. Nothing else was adequate, in our view. When we tested a film being considered we shot it with about a half-dozen models, representing the range of our customers. We ran this over a wide range of exposures, not that we planned on shooting this way, but with thousands of studios open 7 days a week, there was always someone who would shoot all week with the lens aperture wide open, etc. So we want to know ahead of time if this is a potential problem.

When we evaluated the results it would be in a large color booth, maybe 12 or 15 feet wide with neutral colored walls. It's large enough to lay out 40 or 50 8x10" prints, and allow 3 or 4, or more people to all sit in for review. We critically evaluate the skin tones for good reproduction and color crossovers. For example, perhaps a person with a very dark complexion gets slightly bluish highlights: we say, where are the other exposures? Let's lay them side by side; does it get worse in certain conditions? Ok, let's color correct out the bluish highlights and see what happens... So and so, would you rerun a set of prints on this? Pull out 1 cc of blue, and let's try minus 2 cc at the same time. It'll be an hour or so to get the prints, so lets meet back here after lunch, ok? And this is how it goes. If it's a paper we're evaluating, then it's also, so and so, would you get some image stability tests started (it's gonna be a couple months for even preliminary results)? And we wanna run latent image shift tests to see if the time delay between print exposure and processing is a problem (we ran 500 to 600 ft rolls of 10" paper, and it can take nearly an hour to expose the full roll; so it could potentially go onto a processor with some images only 10 minutes old, but others nearly an hour).

Something else we include in the test scenes is a selection of colored fabrics - strong red, green, and blue colors, as well as some smocks the models can wear. When we lay out prints in the color booth we'd also bring over the real fabrics. Most of the time they are a close match for the actual fabrics (except that the real fabrics laying on the countertops have folds in them). People here may think, that's not very important. But when a mother has picked out a certain pastel colored Easter outfit for her little girl, she doesn't want a different color on the photo.

I've been digressing, but my point is to give an idea of what we go through. So if someone says, "hey! Let's test with an out-of-spec film process!" well, no, we're not gonna do that. It's such a touchy, finely tuned process that it seems obvious that an out-of-spec film process is gonna bring in color problems somewhere - how could it not?

But to finally get to this point of comparing: we had rolled out a certain printer - a high-quality dye sub machine - in a number of local studios. I'm acting as an in-house product manager for it - I've made special ICC profiles for it, as well as an exposure correction routine for studio use. Anyway, here's something I've done maybe 50 times, always with the same result. I stop by a studio to see either the manager or a senior photographer - whoever they see as their "expert" for onsite printing. I have them pick out a good example of a portrait session on their system - one that they think might be difficult. They're gonna do their best with it - whatever adjustments they think they need to make (they always think that every sitting needs their personal adjustments to be its best). So they make adjustments and spit out an 8x10" print. Are they perfectly happy with it? If they think, maybe a bit more contrast would help, I say to go ahead, then we make another print (I have to let them "charge it" to my department). When they finally get the best they can do, I pull up "my system" on their computer (IT has previously loaded it remotely). Now they just have a few clicks to choose from - it's fairly obvious which is best. We print it, and now the question is, which print do you prefer? Every time they pick mine, and there is no doubt about it - this is the one they want. Up until that moment they thought that they had the "best;" now it is no longer good enough. And the whole thing is - they didn't have "better" to compare against.

So I think the same thing may well happen during the one-shot processing. Now if it's a subject matter, such as a landscape, etc., where there is not a predetermined, set way that it should appear, then it probably doesn't matter much. But when it's a studio portrait, there's really a fairly narrow range that is "best." Most people won't see it with a single print - they can adapt to just about anything. But if they have a handful of variations to choose from they generally pick something in a certain range.

Anyway, I think it's generally a good idea for someone who plans to run C41 with sparse amounts of developer to run at least one set under "good" conditions. And don't think that a control strip will predict the results. They're typically just several neutral patches - they don't show complex interactions between dye layers when different colors predominate. We used to run something like 40 control strips per day, but when we want to know how a certain color reproduces we photograph and print it.
 
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