Interesting idea.
Despite the former Tetenal Magic Box we've seen offers from the chemistry manufacturers as 1L, 2.5L and 5L kits.
Looks like there has been sufficient demand for them, otherwise the producers would not have offered them.
My personal experience is that most color kit users are doing batch processing at home: They collect their exposed films, and when they have enough for a complete 1L kit for example, they process all at once, in one batch / run.
If 500ml is indeed the perfect volume, fitting the needs of the huge majority of curent users, then the 2.5L and 5L kits might fail in the market in the future.
We will see: If those higher volume kits are still offered in two years, then 500ml has probably not been the perfect size.
Ι bought the bigger kits also. I did so not because they fit my needs, but because there was nothing else more convenient and i didnt want to give my rolls to unreliable labs anymore. I believe several e6 users are in a similar position, they just don't have a better choice.
I also wouldnt mind a 500ml kit being a bit more expensive per roll. And if i need 1L i can still buy 2 500ml kits and keep the second sealed and fresh until the very moment i would need to use it.