Hi,
Uprating a film doesn't mean you are changing it's sensitivity to light (film speed). It just means you are lying to your light meter and saying that you have a faster film, when you really do not. Thus, when you uprate, all you are doing is underexposing the film by using an EI that does not match the ISO film speed.
So, Tri-X at 25,000 is SIX stops underexposed (25K, 12.5K, 6.4K, 3.2K, 1.6K, 800, 400). Think about what that means in terms of tonality. Everything shifts down 6 notches on a gray scale. This means that anything not distinctly brighter than middle toned in the composition (above Zone VI) will be rendered without any detail, texture, or even any tone. I.e. everything will be pitch black except for things that were quite bright at the scene of exposure. And there is absolutely nothing you can do in printing to put texture or detail back there. It also means that the brightest whites in the composition will be exposed as middle gray at best. Therefore, anything between middle gray and the brightest whites will be dark shades of gray.
Pushing your film can only do so much. It is limited by what is placed there with exposure in the first place. Pushing most affects the areas that have received the most exposure, and vice versa. If middle gray is the highest anything was placed with exposure, that can only be raised so much by pushing. And Zones 0 - IV, where most of the printable area of your picture will end up falling, cannot be pushed all that much.
BTW, ISO 25,600 is a digital-only number. ISO never specified details for speeds over 10,000, I believe, but something they published at one point suggested that if they had, they would have gone to 12,500 as the next number, not 12,800. So, I think EI 25,000 is the best way to refer to it when speaking of film.
At any rate, stand development is exactly what you don't want in this situation. You want aggressive agitation in a strong, speed-supporting developer. Diafine is great at supporting the low tones, but won't do much to punch up the high end. I might use Microphen. Or, I might use Diafine followed by Microphen and see what happens!