According to a post by Gerald Koch (September, 2003):
"Gradol is the hemisulfate of p-aminophenol C6H7NO.1/2H2SO4 and has a molecular weight of 158.14.
Does p-aminophenol leave a stain? I dont recall seeing a stain when I used Rodinal. When I get home I will look for negatives from the 60s that were developed in E20 to see if I can a stain. From what I recall the negatives are on the thin side but print well.
I wonder if it might be the ...sulfate. You know, sepia toner is sodium sulfate.
I'm looking forward to the results also.
....this is about kodak's curves.
I just tried mixing up an Edwal 20 type in these non scientific amounts-
This is for 1.5 liters so keep that in mind...and this is not in the amounts given on the internet or in the FDC by Anchell.
pinch of metaborate to preserve the P-aminophenol while mixing
10g P-aminophenol
135g SS
10g Boric Acid
15g PPD
10g Borax
10g Glycin
20g of Sodium Hydroxide (needed to be added for the Glycin to go into solution. It went into solution at 140º F, but came back out when it cooled so I added the hydroxide.)
The Borax/boric acid combo hopefully will act as a buffer since I read somewhere the developer is sensitive to Ph. I haven't really tested it fully yet. It has been really hot here so the one roll I ran after seasoning it (with 3 rolls 35mm) was a little overdeveloped at 7min @ 25º F. (APX 100). So far it looks like it holds the film speed really well. I have a bunch of film to process from a recent trip, and I will post some of the results afterwards.
If anyone has any comments on the above formula let me know. I would love to hear opinions from others.
I haven't mixed up E-12 yet, but I have always had an affinity for p-aminophenol so I thought I would try E-20 first.
Patrick
I had problems with chemical fog with this developer as it was mixed on most films, strangely enough not on APX 100. It is an interesting developer after I added some KBr to get rid of the fog. The standout quality is the grain. Oodles and oodles of it, probably due to the pH since I added the hydroxide. Here is a shot on Fortepan 400, which is a terrible film, but it shows the grain I am talking about.
I am going to try E12 next.
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