My Leaf digital back actually gives a readout of the detected shutter speed, but that doesn't really work for a standard fixed-sensor camera. It sounds like you'd need to take photos in a very controlled environment, i.e. an 18% grey card in a studio, with a recently calibrated light meter, take a spot reading off the card, set the camera to that setting, take the photo, and review that the grey is recorded as middle grey. If its brighter, your shutter is too slow, if its darker your shutter is too fast. If you want to know by how much, you may want to take several shots with larger or smaller apertures, but the same shutter speed, so you see where the gey fall with exactly half or twice the light. from that you should be able to best guess the inaccuracy.