I might have a few contacts in that world

(I'm a lens designer by profession, with a fair amount of practical experience in optical shops)
How to obtain a "suitably-radiused" one?
I think of casting a negative form, but all materials that come to my mind have some shrinkage. The ideal polishing cup should be a bit larger to take the layer of grinding medium.
You don't have to hit the radius of curvature exactly with your tool base. Use a thicker layer of pitch (I'd start at 3/8" thick), and press the pitch long enough to form. For a one-off job I'd buy a cheap COTS lens (like a plano-concave) from Edmund Optics or whatever with similar radius of curvature to use as the tool base. Pour the pitch, scribe it, then attach a wooden dowel to the back of the tool with epoxy or optician's wax. Voila! Easy-peasy.
BTW, it's easy enough to send off to a place that will strip the coating for you. The OP mentions DIY. For the DIY'er, going through this exercise will provide very interesting experience in the world of pouring pitch and polishing optics. One tip: Don't use your wife's favorite kitchen pot to melt pitch.
P.S. Texereau's book "How to Make a Telescope" is a very good reference on polishing techniques. The second half of the book on mounts is kind of dated, but the first half is pure gold. His description of making the pitch lap and polishing strokes has relevance here.