IMO it's more difficult to see it, it's always more difficult to see anything in the view camera GG than in a convenient viewfinder of a SLR
But but you can always adjust well the cross-polarization in the GG, just look at the glares in the scene from sunlight to rotate the filter. As always Pol do nothing if illumination is not polarized, in an overcast sky Pol acts mostly as a Neutral Density filter taking 30% of the light. Direct sunlight is Polarized by the Earth's magnetic field, but an overcast sky destroys the light polarization.
Personally, sometimes I did something to adjust the polarization degree (angle to the top cross polarizarion), as I use a DSLR to meter I find the angle and I use the same in the view camera. Anyway you simply can compare what happens in the SLR/DSLR view finder (as you rotate filter) to see how the same looks in the GG, to learn better the effect.
With Velvia it darkens sky, preventing local overexposure. In general Velvia is saturated enough, but...