At some point, the lens was subjected to sufficiently high temperature long enough for the oil component of the helicoid grease to separate from the thickener (referred to as “soap” in the grease-making industry). Once separated, the oil can slowly seep out and foul the aperture blades.
The drag (stiction) imposed by the oil between the overlapping aperture blades is too great for the closing spring to overcome on a spring-closing aperture, so the aperture first becomes sluggish. As the fouling increases, the oil will start to oxidize, making the oil become increasingly tar-like. Eventually, the diaphragm becomes immobilized.
This most often happens when the lens is left for hours in the interior or trunk of a hot, closed vehicle on a sunny day, stored in a shed, or if it is left on a heating radiator during the winter.
From Google using the search string “
heat effect on grease:”
“When exposed to heat, grease will tend to separate, with the oil component thinning and separating from the thickener, leading to a loss of lubricating ability, increased friction, and potential damage to the components it's meant to protect; essentially, excessive heat causes grease to “bleed” and become less effective as a lubricant.”
The following is a useful article about the properties of various types of grease.
https://reliability.com/resources/articles/understanding-the-basics-of-grease/
An important consideration with grease intended for lens helicoids is the significant amount of mating surface area. Both male and female helicoids are usually made of aluminum, soft and relatively delicate. So, they must be lubricated. But to keep the resistance low enough so that they will move freely requires a relatively thin grease. The most suitable grease I’ve found is the helicoid greases #10 and #30 sold by Japan Hobby tool.
#10 is the thinnest and is a good choice for cold weather use. #30 is medium and the best choice for manual focus lenses in average conditions. Since these greases are miscible, you can mix them to achieve intermediate densities. I stipple the male helicoid with small dabs of #10 applied with a toothpick and then use even more of the #30 for an intermediate result.
https://japanhobbytool.com/collections/camera-repair-material/products/hg
It’s pointless to apply a copious amount of grease because there is little clearance between the male and female parts. Any excess will simply be pushed out of the ends and make a mess.
There is a problem with simply dissolving the oil on the diaphragm with a solvent, and mopping out the oil-plus-solvent liquid. This will free the aperture and allow it to work normally. But eventually, the heat-damaged grease will continue to weep more oil. That will foul the diaphragm again. The damaged grease must be entirely removed and replenished with fresh, undamaged grease for a permanent repair. Then, so long as the lens isn’t re-exposed to prolonged excess heat, the problem will most likely not recur. My lenses that I’ve cleaned of oil-weeping grease and relubricated as described have not had a recurrence of the problem. I’ve only encountered this with second-hand lenses, never with any that I bought new.