Is there really much to be gained from Pyro , FX 55, and other mix yourself etc developers over stock developers such as ID11, Microdol X , Accufine ,etc?
You can get very good results with standard, manufactured developers. IMHO people should master one of these before trying any roll-your-owns.
But mixing your own developers opens up an entire new world for tweaking things - for better or worse. It is also much, much, much cheaper than buying premade, at least in nations where chemistry is readily available at good prices.
I started out with Microdol-X and D-76. Well ... I actually started out with Dektol in a Tri-Chem pack, but that's an entirely different story.
I eventually moved to HC-110 because that's what all the Kool Zone Photographers were doing.
Then, I discovered PMK Pyro. To this day, it remains my favorite for photographs with clouds because of the distinct edge effects it provides.
Then, I discovered DK-50 which I played with for a while to understand what our grandfathers were using.
Then I discovered roll-your-own D-23 and Pyrocat-HD and this, in turn, fired off a multi-year exploration of still/standing/low agitation, high dilution development.
I'd say that D-23 and Pyrocat-HD are the most versatile of all developers I've tried. They can be used in so many different ways and diluted so many different ways, they constitute a
family of choices. I've never tried Rodinal, but I'm told it's much the same story there as well.
tl;dr Learn one developer and one film REALLY well, they change one or the other to try different things.