Sintra is PVC compressed into a solid sheet. usually you can get it in sizes up to about 3/8 inch thick, which is what we use where I work. We mount large graphics and photos to the stuff, generally with coldmount adhesives. If it's being produced outside, we spec out a laminate overcoat for the photo as well, to protect the print on display. Sintra is a neat material to work with, it can be used like a sheet of plywood and is very good for mounting to walls or doing profile cutouts on as well. It's drawback is the expense, expect to pay around 100-120 dollars a sheet.
We have also used aluminum, MDF and gatorboard. Gatorboard can offgas over time, so they seal the edges of the board, if it's used in proximity to artifacts. MDF is loaded with all sorts of bad things, but makes a great substrate to mount to, it's only slightly less expensive than Sintra though, and really heavy. Aluminum--generally they mount to that and then wrap the corners by using an overlaminate. in the old days--the photo dept. I work for, made murals in-house with kodak mural paper (fiber) and they used wheat paste to wet mount the paper to plywood. the corners of the paper were folded over the edges and tacked, or stapled, to the back of the plywood. when dry, it was literally tight as a drum. We still have some of these, they're probably 30-40 years old now, and showing their age, but they're not on display anymore. I guess the problem is that most of these adhesives are permanent for one thing (not archival in a conservation sense) and then the substrates are all building products more or less. It could be that you use the conservation matt board as suggested, then use something like Sintra or Gatorboard or whatever as the backing material. There are some products like the microchamber zeolite stuff, that you can coat like a paint onto a surface. It could be that you could make a barrier of sorts between the backing board and the substrate. But then the problem is how to hang it--it's need to be framed in somehow. When you flush mount to one of these other substrates, they're heavy duty enough to just mount that to the wall. Another old-time technique though, again not really "archival", is to mount the print itself to the wall. We did this with fiber murals once, wet mounted them to the walls of a gallery--they looked great, but were totally destroyed on de-installation. I don't know really, how to do it "archivally"...but I hope this gives you some ideas, or maybe some ideas of things not to do...
my opinions only/not my employers.