To meet aims of speed, contrast, fog and other image quality criteria, a strict adherence to the Kodak guidelines are needed for quality control. However, there are variations in the numerous control graphs showing what pH does outside of the exact "ideal". The pH value is one of these. However, a variation of + or - 0.01 or 0.02 pH units is not very significant in the face of a variation of + or - 0.1 or 0.2 g of developing agent, carbonate or hydroxyl amine. So, if the aim is 10.2 with a variation of 0.1, that means that 10.3 is good still, but then 10.4 is not bad.... See the chart for the results as pH varies and it can tell you the story better than this.
Try this for ECN, or look for the C41 version on the EK site:
http://www.kodak.com/motion/Support...ocessing_Manuals/H24_Modules_Online/index.htm
But, pH is very difficult to actually define at the high salt content of the developer and must be measured at an exact temperature or by using a compensating electrode for both of these items.
PE