The glass plate negatives you probably own are made from wet collodion type.
Negatives with a collodion layer were varnished after processing.
This aged "varnished" layer contibutes to image stabitity.
It often lent a brownish- yellow tone to wet collodion plates.
Well - I would guess your negatives should be handled carefully because they seams to be real old....
But beware of danger : Don't use "alcohol"
don't use "aceton" to clean the plates.
Because this cleaning action could bring you in conflict with your institute - better use photoshop.
with regards
PS : The collodion layer is soluble in alcohol and acetone