hrst, you are opening a can of worms here.
Great, that was my intention!
But by Jove, the blue of the sky is always the same since I was a child and, I bet, in the few billions years before I was born. If you look above your head during central hours of the day and the sky is clear of any clouds you always see the same shade of blue ("blue" in photographic terms is actually a bit violet, but I digress).
You just go so wrong here! Firstoff, you have so much conditions here that it is very seldom that they all hold at the same time in the case of photography. For example, how often do we take photographs straight upwards to the sky?
No, our photographs most often show the horizon and up to 60-70 degrees or so. And we photograph on a cloudy or part-cloudy weather; especially I need to mention layers of very thin clouds or more like haze on the sky; it may still LOOK like a sunny day without clouds, but these tiny droplets scatter light.
The system is complex but it consists of simple parts. First, all the blue color IS due to scattering! If the oxygen just worked like an absorbing filter, we would see black sky because there is no backlight (except for the Sun, which is a small spot). Now, you must understand that this scattering does not only provide "blue" in the meaning of something like 440-480 nm. Pure sky blue also has a substantial amount of wavelengths at cyan and green, even at midday, even when you look directly up.
Now, let's make a simplification and say that the color of sunlight is "minus-sky", due to the very same phenomenon that gives the color its color by Rayleigh scattering. You can think the Sun as a white light source in the enlarger, and the sky as a dichroic filter passing "yellowish" (minus-sky) light and reflecting the sky-colored light. Now make this filter very very faint and put millions of them everywhere -- as we look at the complex, we see the surfaces of those dichroic filters, reflecting sky-colored light, but the system also has this minus-sky light everywhere -- after all, it is the very source of the further skyblue scatterings taking place everywhere.
(The very reason why we have different color temperatures in sunlight at different times of day, is that when the sky is near the horizon, the light passes through more of these "filters".)
Now what do you think happens with this minus-sky light? Right, it gets scattered, too, and mixes with the sky-colored light. It scatters in tiny droplets we ALWAYS have in the air. It is just that we have more of those when the air is moist. We have different amount of droplets at different locations in the huge 3D world of the sky. Natural and man-made particles just add the complexity. These particles may also be colored, which adds even more new parameters. Now actually, the water droplets are below freezing point and thus, ice. Surprisingly, ice forms crystals that add even more complexity. Living in a country with last two winters having some very cold days, we could actually see VERY impressing phenomena near street lights at night. This included three huge beams kilometers long going directly upwards and sideways at 90 degree angles, due to tiny ice crystals interacting in the air. This is just to show the complexity and all of this happens all the time in the sky.
But, if it was just sky-color and minus-sky-color light mixing, we would just have neutral density, right? That's the problem with our earlier simplification. Again, it is more complex than this. Oxygen atoms do not ONLY cause Rayleigh scattering, but they also ABSORB longer wavelengths. Due to this mechanism, even in the simplified case, sky-colored light and minus-sky-colored light do not sum up to neutral density or white light. Now, we add the droplets, different thickness of air at different angles of vision, different thickness of air due to different local air pressures, natural white particles, natural colored particles (pollen to start with...), man-made particles...... And as a result, we have a sky color that can be practically ANYTHING within certain limits, of course.
it never ever falls toward cyan - turquoise. Yes, it really does. It is not VERY usual, and it is NOT very saturated, but it's all about combining effects.
(1) We have a slight cyan-turquoise tint in the sky in reality
(2) We photograph it with a film which INCREASES SATURATION (Ektar), so this tint is exaggerated
(3) The film (Ektar) happens to have a trait of SLIGHTLY amplifying certain shades of cyan-turquoise, so this tint is again exaggerated
(4) Our film (Ektar) does NOT have the typical magenta tint we are accustomed with when using high-saturation chrome films that are often compared to Ektar
(5) The user scans the film with a horrible scanner and workflow that does not work, and anything can happen.
While I completely agree that (5) is the most important reason for "problems" reported, we still cannot just explain everything by going all techno.
Color photography is all about understanding color, and I hate it when it is called a "problem", or when color photography is called "difficult" just because the difficulty is in adjusting colors to match a set of UNREALISTIC random rules created by PEER PRESSURE, not by one's own passion for color. Another typical example of this peer pressure is the insane bitching about skewed horizon line, which can happen even if the picture does not even show horizon line but a true slope.
Usually this leads to a situation where people try to "correct" colors that WERE not only correct but also looked good to begin with, without trusting their own sense of color but being afraid that "this might not be neutral" or "someone might complain this is not neutral". To make things worse, this "correction" work is usually done with tools that do not even allow real color correction (such as Photoshop Levels and Curves).
You mentioned the skin color as an another example of a "reference", and you are as wrong as you are with the sky. There is no one, two, three or ten different skin colors. The range of skin tones is ENDLESS and has many dimensions. And now combine endless range of different skintones with endless range of skylight hues with endless range of filtered sunlight hues, and everything you mentioned in your later post...!
No wonder portraits are often made in studio. However, it will be very educational experience to try shooting "neutral" portraits outdoors, because the only way to achieve this will be MODIFYING the light and this includes using at least reflectors, but also filters, fill lights, filters over them, etc. It does not work by complaining about film or camera and then adjusting random knobs in Photoshop.
And, Ektar is not originally meant for neutral portrait work!
But,
IMO, we should enjoy the colors and try all kind of things to manipulate them. The nature is so colorful and has so much to offer, so we don't need to modify our photos to look always the same when the nature does not look always the same.