Kodak D168
B&W Reversal First Developer
Metol 2g
Sodium Sulphite (anhyd) 90g
Hydroquinone 8g
Sodium Carbonate (anhyd) 44.5g
Potassium Thiocyanate 2g
Water to 1 litre
Kodak D67
(Kodak D19 + Thiocyanate)
B&W Reversal First Developer
Metol 2g
Sodium Sulphite (anhyd) 90g
Hydroquinone 8g
Sodium Carbonate (anhyd) 45g
Potassium Thiocyanate 2g
Potassium Bromide 5g
Water to 1 litre
Kodak R21a Bleach...
This formula will produce less than satisfactory positives.
I wish I could enlighten.
There will be published reversal tips in the upcoming new edition of the Darkroom Cookbook / Anchel
It has been a long time since the last answer to this post, so maybe it is too dated. Anyhow, some time ago I made a project, and I developed cine in my darkroom thanks to help from members of APUG. The main problem was that in my country, some chemicals (metol for example) are impossible to find. I managed to complete the process by adding 10g of hypo to 1L of Dektol stock (1st developer) for 8m at 20Cº using TRI-X (super 8) film. The bleach I used was R-9 (1 L water + Potassium dichromate 9.5g + Sulfuric acid 12ml). I remembered I had problems with a potassium permanganate bleach. As a second developer I used dektol without Hypo. Here is a link to the thread:
(there was a url link here which no longer exists)
I know this may not be as technical as I would like it to be, but is one of the most fascinating discoveries I made in my darkroom thanks to APUG. I also believe that I have to give it back some how, and I think that a complete ignorant on chemestry (like me) or a student on a budget (like me) or a third worlder without access to metol (like me) may find this cheap and easy solution helpful.
I Hope someone would read this.
Hi Ian a lot of time has passed since your 2008 response captioned above regarding posting:More to come
AutumnJazz, I'm slowly going through what I have with me, soon I'll post a number of alternative first developers some with and some without silver solvents (thiosulphate/thiocyanate), along with alternative bleaches (that's alternatives to permanganate/bichromate).
For instance one first developer system is rather like using Dr Beers Variable Contrast print developer, the balance of Hydroquinone/metol is varied to increase or decrease the contrast of the final positive.
Plus a variety of Second developers & alternatives to enable users to produce a whole range of different tones and colours in the final positives. This will enable skilled users to have far more control over their output than could ever be possible using a commercial laboratory.
Also ways to improve or modify commercially processed positives. Before dr5 takes offence at that I'm talking about how to improve under or over exposed positives or change image tone & colour on Black & White home processed, Scala, dr5 or any other commercial B&W positives.
Ian
I did post a lot more Reversal formulae in the Resources section, they are under Developers Non Staining.
Ian
These resources state 60 watts, 12 to 18 inches, for about 10 seconds, or 150 watts at 4 to 5 feet. Is 2.5 min with a 500 watt bulb too much? Is there a way I can tell if the exposure was too long? Want to be safe before I attempt this. Using 16mm Kodak 7266.
As I mentioned on another reversal thread, dichromate bleaches are no longer recommended. Dichromate is highly toxic and most waste disposal systems have regulations against its discharge. It is also believed to be carcinogenic. Potassium permanganate is much safer and is readily available from suppliers of water softening supplies. It is recommended by Ilford for their reversal process. Permanganate will work but you must follow Ilford's directions closely. The following site describes their method and gives formulas.
http://www.ilfordphoto.com/applications/page.asp?n=90
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