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How do I know my base chemicals are outdated??

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Hey guys its just a simple question. How do I know my base chemicals are outdated??
I do as Ralph says, with all of my raw chemicals, but this only tells you when you bought it...

The only advice I can give you, based on my asking, is to try a small amount of the formula and see if it works...

Not much of an answer I know, but everyone seems to give different lengths of time when asked as to how long their own chemicals have lasted. Some say Metol is 'off' when it goes from white to brown, whilst others say that they've had theirs for decades and it's gone brown and it still works fine.

Best I can give you I'm afraid.

Terry S
 
Fixer: smells sulfur-y, something precipitates (although some have claimed to still use such fixer with no ill effects, I wouldn't risk it).
Developer: no longer develops (to normal contrast).
Stop, wetting agent, most toners: never go bad.
 
For sealed packaged powders if they are not discolored and still flow freely they are perfectly OK.

For sealed liquids they are probably OK if not discolored or haven't thrown a precipitate.

Some chemicals, notably Xtol stock, were prone to 'sudden death' syndrome. It was traced to iron in the water but I mix developer using steam distilled water and had it happen to me. For working strength film developer it can be a good idea to do a snip test first.
 
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The XTOL sudden death thing was not due to iron/Fenton oxidation (XTOL always contained an effective cheating agent for that). It was traced to a problem with the small (1l) packets.

I stand (er, sit) corrected. Explains the distilled water & sudden death. I just gave up on Xtol at that point.
 
Hey guys its just a simple question. How do I know my base chemicals are outdated??
Do you mean, base chemicals, i.e. individual ingredients to prepare a developer from scratch? I have old bottles of hydroquinone and metol that are 40 years old and still work. KBr doesn't go bad, full bottles of sodium sulfite are stable away from air. Sodium thiosulfate penta hydrate keeps well in a proper bottle.
 
Do you mean, base chemicals, i.e. individual ingredients to prepare a developer from scratch? I have old bottles of hydroquinone and metol that are 40 years old and still work. KBr doesn't go bad, full bottles of sodium sulfite are stable away from air. Sodium thiosulfate penta hydrate keeps well in a proper bottle.

When I was 14 in 1960, my photo store sold sodium thiosulfate penta in supermarket brown paper bags, ten pounds for about $5. I stopped using the stuff before I used up that last bag, and still have a couple of pounds in that bag. Last time I checked, it was still good to go.Most "base chemicals" are stable and will last nearly for ever if kept in a dry, cool environment. Re metol, I have some really old stuff which is brownish but still works fine. Also have a newer container, still white. Similarly, CD-3 and CD-4 seem to never age out (thank goodness).
 
Well i have learned to look at the packaging they come in. Some companies are easier to trace by how packaging has changed.

Otherwise, if you end up with chemicals that come with a used enlarger,, it is not a generally good idea to use chemicals that have newspapers or advertising material that predate 2000
 
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