Thank you to everyone for taking the time to answer my question. There is a wealth of knowledge here, and subsequently a huge diversity of ideas. Unfortunately I have my hands tied as the sink has not only been made out of MDF already, but is currently in situ in a counter-top and work-surface.
Bob, thank you, I appreciate your advice knowing you've constructed some huge sinks (remember if that vacancy in your house ever comes available...) I'm sure West systems is an excellent medium, however their agents here didn't recommend using MDF to me at all, which brought me back to square one. Maybe when I build my next darkroom...
Matti, the suggestion to use paint over epoxy was that of West System's agent in Ireland I appreciate your saying it wouldn't be suitable, but I'm simply passing on the information made available to me.
Jon I do intend to use a couple of coats of Marine varnish on the existing MDF, and hopefully as you said, it should be sufficient for a personal darkroom.
Bob F I did some research on the fibre glass option, but it was turning out to be elusive and expensive. The MDF as a base however is the premise I'm counting on for the finished sink!
CBG thank you for your obviously very informed advice. I appreciate that you wouldn't recommend or do it this way yourself, but as I explained, I'm working backwards and therefore am limited with my choices. For others out there who have yet to embark on their sink making, yours was extremely detailed and helpful, thank you.
Bdial, Fintan and David thank you for your advice and taking the time to answer the thread, they were all helpful and even if not the solution to my problems, I'm sure someone out there will benefit in some way.
As for the outcome? I've decided to go with a Perspex insert sink into my MDF base. A 4x4 sheet costs just 40 and an adhesive called Dead Link Removed which was recommended to me as an adhesive and sealant suitable for aquariums.
If I spring a leak within a short space of time however.. you all have my permission to say "I told you so".
Thanks again to everyone,
Síle