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Harvey's 777

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"Shadow dumping"

Maybe this is obvious, but I believe the meaning of "Panthermic" here is that the contrast curve is not affected over a range of temp's when the time of development is adjusted accordingly, as apposed to a developer where the linear adjustment of time breaks down over an extended range of temperature. Not "Panthermic" as in Diafine where temperature does not affect speed or contrast and you develop the film for the same length of time over a wide range of temperatures. So could the problem with the "shadow dumping" be simply underdeveloped due to not correcting for time? Again, not trying to insult anyones intelligence.
 
MMfoto said:
"Shadow dumping"

Maybe this is obvious, but I believe the meaning of "Panthermic" here is that the contrast curve is not affected over a range of temp's when the time of development is adjusted accordingly, as apposed to a developer where the linear adjustment of time breaks down over an extended range of temperature. Not "Panthermic" as in Diafine where temperature does not affect speed or contrast and you develop the film for the same length of time over a wide range of temperatures. So could the problem with the "shadow dumping" be simply underdeveloped due to not correcting for time? Again, not trying to insult anyones intelligence.

You've picked up the gist of the puzzle. Here's an old time/contrast chart:

http://unblinkingeye.com/Articles/Harvey/C02/c02.html
 
MMfoto said:
For God's sake. All this speculation is killing me. Can anyone identify a "bit" of Glycin under a microscope. Or is there a test that can be run to determine if there is indeed Glycin in 777?

A microscope won't do it.
when I did it (I reported it in an old APUG thread) I used Mass Spectroscopy
 
Hello Jay -

I'm shooting 135 and 120.

I plan on storing the 777 soup in a 2 gallon storage tank, with a floating lid, snap on lid and spigot. I toying with the idea of half submerging a glass aquarium heater in the soup,, that can be tuned on to heat the developer to 75F when needed. The actual developing will be done in a 4 or 6 reel tank, which I will use 2-3 rolls in, with as much developer as I can fit.
 
"777 has a giveaway smell--nice but very distinctive."

I think the smell that is refered to is that of the ppd which is described in some texts as pleasant. Catechol has a "medicinal" smell. AFAIK, glycin is odorless as is hydroquinone.

There are qualitative chemical tests for developing agents. One involves the color generated with ferric chloride. However, before testing one must remove any other developing agents which can mask the result. I believe that there is a chapter in P. Glafkides, Photographic Chemistry, Vol 1, describing how to identify the common developing agents.
 
df cardwell said:
predictable speed and contrast from 65 to 90 degrees.
.

It's probably just the point where the straight line becomes the toe and the curve changes. And my thermometer could be wrong.
 
its too bad they don't sell already depleted developer in a jar along with the chemistry to make the stock solution. it would really help their customer base realize what a great developer 777 is. i wouldn't be surprised if 1/2 of the people who buy it give up on it because their first sheets+rolls are too contrasty and not what they expected to be.

you might decant a bunch of developer and use it over and over to exhaust it a little bit, and mix it back into your stock solution. it might take more time than having a jar of "the good stuff" mailed to you, but it should do the trick.

good luck!
john
 
jnanian said:
its too bad they don't sell already depleted developer in a jar along with the chemistry to make the stock solution. it would really help their customer base realize what a great developer 777 is. i wouldn't be surprised if 1/2 of the people who buy it give up on it because their first sheets+rolls are too contrasty and not what they expected to be.

Its recommended to develop some scrap film first to "season" a new batch.
 
Does the seasoning process have to do with the soup becoming silver enriched?
Does a compensating effect occur? (is silver floatsam deposited on the negative
as it is developed?)

Harry Lime
 
jdef said:
John,
the "seasoning" effect is due to the accumulation of developer products, and not aerial oxidation. Edmund Lowe gives some alternatives to this method of seasoning, which involve the addition of a small amount of potassium thiocyanate or thiourea to the fresh solution. There is also the question of backing dyes, and their effect on a replenished system. It is generally advised that these be removed in a bath of sodium sulfite before development. The fresh solution might be better suited to expansion development, and reserved for that application until seasoned.

Jay


thanks for the explanaition jay.

not sure scientifically or technically why it helps mellow it out, i know
from printing thousands of sheets if 5x7 xxx in dk50 (back in the day) that it was *essential* to leave about 1/4 - 1/3 a tank of depleted developer in the tank ( sediment and all ) whenever a fresh batch was mixed. if we didn't do this we wouldn't have had the long tonal range negatives we had, and the film would have been way too contrasty ...

from the essay the unblinkingeye, it sounds like 777 is sort of similar.

-john
 
Crawley suggests the reason ripened PPD developers work better is that partly exhausted PPD slightly encourages edge effects.

Lowe, in 1939, was quite clear on the matter, and illustrated it with photographs of the grains: finer grain ( classical fine grain: regular, concise; not clumpy or mushy ) came from seasoned developer. He attributed this to the restraining action of the bromide and accumulated developer oxidation byproducts.

This has been de rigeur for any replenishment line, running Diafine, D23, or Edwal 12. Or, ahem, Xtol. E-6 lines have always used a "starter" for new developer in an un-seasoned line.
 
In Houston, in the summer

So, how do you guys heat your 777 to 75F?

waterbath?
Aquarium heater?

Anyone?

Harry Lime

Along the Gulf coast. From May to Thanksgiving. Add ice. Lots of ice.
 
"Shadow dumping"

Maybe this is obvious, but I believe the meaning of "Panthermic" here is that the contrast curve is not affected over a range of temp's when the time of development is adjusted accordingly, as apposed to a developer where the linear adjustment of time breaks down over an extended range of temperature. Not "Panthermic" as in Diafine where temperature does not affect speed or contrast and you develop the film for the same length of time over a wide range of temperatures. So could the problem with the "shadow dumping" be simply underdeveloped due to not correcting for time? Again, not trying to insult anyones intelligence.

Correct! More accurately, UNDER-AGITATION. The person who claimed this fall off at 72F neglected to heed my Unblinkingeye caveat and warning about agitation.

Fred
 
thanks for the explanaition jay.

not sure scientifically or technically why it helps mellow it out, i know
from printing thousands of sheets if 5x7 xxx in dk50 (back in the day) that it was *essential* to leave about 1/4 - 1/3 a tank of depleted developer in the tank ( sediment and all ) whenever a fresh batch was mixed. if we didn't do this we wouldn't have had the long tonal range negatives we had, and the film would have been way too contrasty ...

from the essay the unblinkingeye, it sounds like 777 is sort of similar.

-john

I also used DK 50 in a fashion similar to yours. 777 is similar but not the same. The 777 is not really depleted, it is byproduct saturated when it needs to be changed. Ugly stuff, but it still works as intended. That is why we used the term "ripened". A level of those byproducts are desirable, to a point.

Your stressing *essential* cannot be stated loudly enough. It is much simpler to tame 777 and only a few sheets or rolls can get it in balance. Today's somewhat compromised t-grain films may not work too well, or produce the intended effect. I don't know since I can't really find any reason to use most of them.

Fred
 
Any hints about mixing this stuff? It appears that one of the components is quite toxic, so I will use rubber gloves.

How about replenishing? I've only ever used one-shot developers, so any information would be appreciated.

I shoot Tri-X@400 in 135 (and some 120) 90% of the time. Does anyone have any experience with this combination?

Can you push process Tri-X to 800 or 1600 in 777?

Is 777 closer to XTOL or D76? Someone told me it's similar to Pyro...
This may be a difficult question to answer, since the formula is secret, but perhaps someone can speak from experience.

Considering the advances that have been made in the past decades (XTOL etc.), is 777 still worth the effort? I know there is no such thing as a magic bullet in photography, but 777 sure sounds intriguing.

How about development temperature? I read somewhere that it works best at 75F. How about room temperature (68F)?

777 is supposed to be very sensitive to agitation. Anyone care to share?

How about the ripening process? How does this work?

Oxygen in high concentration is toxic, 777 in normal use is not. It will stain, which is to be expected from the formulation.

About there being no MSDS, 777 prcededs those by about 40 years and most of the heavy users of the stuff are still around without ill effect. A few have succombed to the real perils of political assination, falling off mountains, High Fructose corn syrup, an irate spouse or two, and one to an overdose of lunatic postings of utter nonsense on public websites. But hundreds of heavy bare handed 777 users are still with us. Rubber gloves can keep your fingernails from discoloration if you are prone to immersing your hands in deep tanks for a protracted length of time, so do use them.

(there was a url link here which no longer exists) has it right in every respect, his description of how it works is perfect.

777 contains paraphenylenediamine, True, and also true of every C 41/EP 2 type color process, and every mini lab at you local wal*mart. (I think the levels are about the same if not higher in the color developer) The danger with the color chems is that they are shipped as a concentrated liquid and are heavily diluted for use. Not the case with 777.
Published photographs made with this developer look very, very nice and do seem to have a certain glow. But I'm not sure that this couldn't be done with another developer.
One can search for what we don't know or use that which we do know.

And, we do already know that Edwal-12 and some others do produce a similar look.

The formula which Ed published at unblinking eye was at the time admitted to be at best, a guess, and at the time none of use knew what was the fate of BPI nor that they would still be around 7 hours not to mention, 7 years, later. Since it is easily obtainable, stick with the BPI compound. Getting PPD is not only not that easy, in small quantities it can be relatively expensive.

777 does contain Glycin, the use of an alternative naming convention may provide BPI with plausible deny-ability, but what they make contains what we call Glycin. A good thing.
Is 777 closer to XTOL
That question is inverted, both in time and logic.

There are so many remarkable developers easily available each with very special capabilities, I have yet to find a reason for Xtol or even HC-110. Neither are a compelling improvement on ID-11, Rodinal or a host of others. There have been few, very few, advances in film developers over the 1930-1970 halcyon days just marketing opportunities. Not just developers. I find little use for t-grain films either. They contradict the strengths of B&W. Grain can be a creative element. I am equally comfortable with a 6x6 or 4x5 as I am with 35mm. I don't shoot weddings nor use direct on camera flash and burning out big white dresses is of no concern. I purely do not want a B&W film which replicates the response of a color negative film. I rarely use those either. When I do a project in B&W I usually have between 10 and 50 rolls (120 or 35mm) to process at a time. A one shot developer makes no sense in that case. It is either a test session and/or very rare that I have less than 5 rolls of 120 to develop and a big deep tank is easier and better understood than even my Jobo ATL. The JOBO is for E-6.

The biggest selling point for 777 in the old days was to produce the same negative on Monday morning when NY loft buildings were unheated at night and as you did on Thursday when the developer may be 15F warmer. 777 works just fine at 65F as it does at 85F and it will produce identical results. You just cannot be at all timid about agitation regardless the temperture.

777 is not the best choice for more than a mild push of film speed. It can be done, that's for sure, but there are more specialized developers better suited for that use. It works great if you wish to pull the speed or intentionally overexpose and develop normally. The highlights resist blocking up.

Why store the replenisher in a tank instead of a bottle? Keep the air to a minimum, it lasts a very long time and you use very little.

Give it a try with or without the rubber gloves.

Fred
 
Correct! More accurately, UNDER-AGITATION. The person who claimed this fall off at 72F neglected to heed my Unblinkingeye caveat and warning about agitation.

Fred

The person would be me. I'll go back and read your article again.

In any case, I can't thank you enough for publishing that article. 777 gives my photographs a look that has eluded me for 40 years. I rarely use any other developer now. I hope BPI can stick around for a long time.
 
I'm up for Magic Bullet chasing.

Where exactly can one buy the Magical 777 developer? Bluegrass Industries only offers an adress and phone number online. Must I call them? The Frugal Photographer offers 1 gallon bags for the unfrugal price of $27. What quantity will Bluegrass sell? Price?

Once we settle that, I'll be back with particulars about storage and replenishment and agitation and Jobo tanks.

Thanks for all of the information. It's been fun. Now it might be time to get down to business.

Wayne
 
777 is very similar to W665. 777 is using PPD while W665 is using OPD.

PPD is staining everything while this is not the case with OPD. Further OPD is less toxid.
One of the differences is that W665 is forming a solarisation layer which must be removed by Acetid Acid of Hydrochloric Acid.
W665 was after WWII sold under Perutz W665 and it's an ultra fine grain developer just like 777 is.
You will have some loss in film speed but in return you get very fine grained negatives back.
W665 is about €9,75 for a 700ml stock solution.
 
Where exactly can one buy the Magical 777 developer? Bluegrass Industries only offers an adress and phone number online. Must I call them? The Frugal Photographer offers 1 gallon bags for the unfrugal price of $27. What quantity will Bluegrass sell? Price?

Wayne

I admit the initial price of 777 taxes my budget also, but it really is not that expensive considering at the very minimum the lifespan is at least a year. This is a gallon. A gallon of replenisher is good for about 150 rolls and many one shots at that rate, cost more. Last I checked the BPI price was about the same as Frugal, and yes you must call them.

It may be a bitter pill in some ways, but there is a need to maintain in business the good folk who continue to make these low volume, and rare products available. They should be thanked, not resented.

Consider the alternitive. Look at what has happened since Wal*Mart and Home Depot eliminated all your local made or owned, neighborhood, independent, purvayors of anything. The costs have gone way up, and the number of brands, the variety, your ability to make a choice, is less than a tenth of what it used to be. The prices in the sale flyer, and the huge jars of pickles are an illusion. The low volume, unadvertised items have gone up by 300% or more if you can get them at all.

I was a consultant to Kodak and Minolta, and serviced the photography needs of the business magazines when this market lunacy began in the photo biz and it was the consumer (except in the case of hapless Kodak) who let it happen. They responded like idiots unaware of their own self interest while they rewarded the excesses, greed and abuse of the wall street wannabe class who drove us into this irrational hole.

$6.25 a quart for 777, when you look at what is going on all around you, is nearly a bargain. Drop into the convienance store attached to any gas station and be aware that the bottled water costs more per gallon, than the gasoline.

Fred
 
Hello:

Am thinking about developing Agfa Scala in 777. Any thoughts or suggestions would be appreciated.

Donald
 
Where exactly can one buy the Magical 777 developer? Bluegrass Industries only offers an adress and phone number online. Must I call them?

Bluegrass has no e-commerce website and they don't take credit cards. So you have to call them, have them price your minimum 4 gallon case order with shipping and then you send them a check. I've found this process more than worth the trouble.
 
I can't wait to try 777, perhaps in a new darkroom I could set up large tanks. How large of tanks are most of you using?
 
Can someone supply the full name of BPI, and the phone number please. Thanks.
 
Thanks Fred and c6h6o3. It sounds like the 4 gallon case is less than individual 1 gallon orders. I will have to figure out how to store 4 gallons in my little apartment. Wine in a box bladders is one way.

Replenishment:
The Frugal Photographer says to add 1.5 oz per 36 exp. roll of film. I'm not sure that I loose 1.5 oz. when I develop a roll. If not, do I pour out a bit to make room for the full 1.5 oz.?
Pre-rinse: Currently I pre-rinse all my film for 5 minutes prior to developing in Xtol 1:3. I don't know that it helps. It doesn't hurt. 777 and rinsing the backing off: Good or bad?

From The Frugal Photographer:

"Agitation

Agitation during development has a marked effect on negative quality.
Continuous agitation is the only way to achieve exact repeatability and
optimum density. Agitation should be continued in stop and fixing baths."

I have the hardware and I like usung Jobo tanks and a Uniroller motor base. Good or Bad?

I really appreciate all the help. I won't jump into this overnight. I sneak up on changes like this. In the meantime, Xtol & Rodinal work for me. I plan to investigate Barry Thornton's Two-bath developer also.

Bluegrass Packaging Industries, Inc.
3651 Collins Lane
Louisville KY 40245
502-425-6442


Thanks!
 
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