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Glycin stand development

Stand developing in my Jobo 2400 tank is not up to @chuckroast standards:

A compromise with agitation every 3 min may be called for.
Specks on the film are due to floaters in my GSD-10.

Ha. Not sure they are "my" standards. Moreso, I tripped across the importance of minimal support contact and suspension for gravity to do its thing by means of a lot of trial and even more error.

There are, of course, many ways to do things, I just recommend the approach I use because I know it works and works reliably.

I have a bunch of CHS II sheet film in frozen storage, I really must get to it.
 

I know you're exploring glycin for film and it is interesting to watch. My biggest fear, though, its becoming dependent on a component that is single sourced from a very small vendor.

If you are so inclined, I'd recommend a look at D-23 1+9 with 0.5g/l sodium hydroxide (lye) added used as a semistand or EMA developer. It produces razor sharp images. (Originally suggested by @Raghu Kuvempunagar.)

Another point of comparison might be PMK Pyro which cannot be used in semistand/EMA development because its aerial oxidation rate is so high, but it produces very sharp negatives. For example, here is 2x3 HP5+ done in PMK - scan of silver print:

 
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I have been doing B&W photography since 1965. I know what I am doing. I know how to print and how to evaluate negatives by eye.
 

I agree with your numbers. The ASA doubling in 1960 was a colossal error.
 
Google Gemini:
"In the development of thin emulsion films from the 1960s (such as Adox KB14/KB17 or Efke), glycin is generally considered to produce more pronounced edge effects than metol, primarily due to its unique reaction to bromide and slow development speed."
The last line is confirmed in books, eg, "Developing" by Jacobson.

Since this is a handy list of instructions I propose to determine a stand development time for CHS100 II with Part A modified by leaving out the metol.
Potassium Carbonate Crystalline will be replaced by 62.7 g of the anhydrous version.
 
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I semi-stand developed CHS100 II in FX-2 1+1+18 and also in a version leaving out the metol, call it FX-2nm, 1+1+8 , 1hr 21C and 23C respectively, agitate @30 min.
The glycin only version with no metol FX-2nm shows a stronger edge effect in agreement with the prediction in the post above.

FX-2

FX-2nm

The FX-2nm version may work better with more frequent agitation to try to avoid blotches [mottling] when using glycin alone to get maximum edge effect.
 
I found the best method appears to be a pre-wet for 3m and then low frequency agitation with 5 inversions every 10 min for 60min:

The clouds were not uniform in tone and may account for most of the remaining non-uniform background.
Acknowledgements to the work of Jim Byers on GSD10 blogspot.
The working solution of GSD-10 1:30 is very similar to that of FX-2nm 1+1+8 but FX-2nm is a two solution version expected to have a longer shelf life.
 
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Al
Google Gemini:
"In the development of thin emulsion films from the 1960s (such as Adox KB14/KB17 or Efke), glycin is generally considered to produce more pronounced edge effects than metol,

Alan, in this series of testing, would you also be comparing Glycin developers with Beutler type developers?
 
Can do, to some extent. FX-2nm working solution has 0.75 g/L glycin.
Could try keeping the sulfite and carbonate the same and using, say, 0.5 g/L metol. But the result will not be definitive for all possible variations of Beutler developer.
 
Glycin vs Metol

(1) FX-2nm, 1+1+8, glycin = 0.75 g/L

(20 Metol only version, 1+1+8, metol = 0.25 g/L, sulfite and carbonate as in (1).

The negatives with 0.75 g/L glycin and 0.25 g/L metol are close to the same density. 0.25 g/L metol is similar to half strength FX-1. Semi-stand 1hr 24C ag 5inversions @10m, 25m,40m.
Glycin has notably less blotches.
 
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A test with half the glycin (0.375g/L) shows edge effect notably increased from that in post 63 with glycin 0.75 g/L and mottling appears under control:


At 1hr the negatives are quite thin. I hope to give this a field trial.
CHS100 II EI=100, FX-2nm 1+1+18 , 60m 23C Prewet 3min, Agitate 5 inversions @ 10m, 25m, 40m.
 
CHS100 II EI=100, FX-2nm 1+1+18 , 60m 23C Prewet 3min, Agitate 5 inversions @ 10m, 25m, 40m.

Sometimes the edge effects show fairly clearly:

Sometimes only at higher magnification where there is a line along the border with the sky:

Sometimes with some mottling and runs from sprocket holes which may be avoidable by agitating every 10min:

I believe Only CHS100 film semi stand development in dilute glycin developer will show edge effects to this extent though have never used Pyrocat with minimal agitation.
 
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I'd love to see a side by side comparison with the Savoy building developed in something like XT-3 (Xtol) and processed conventionally as a reference to see how strong the edge effect is.
 

I realise you are doing very specific tests here to try and suss out the edge effect variables - a good on you for doing so.

But I do have an observation, if I may. On my monitor, at least, the images seem contrasty, but dark lacking highlight sparkle. Is that because you're only interested in the edge effects for the moment and are not pursuing best image balance, or is an artefact of the development technique. No criticism intended, just trying to determine if its the development doing this or something else. (Or am I seeing things?)
 
I'd love to see a side by side comparison with the Savoy building developed in something like XT-3 (Xtol) and processed conventionally as a reference to see how strong the edge effect is.

I did what I believe to be a test of this type in post 26:

"Two forms of apparent sharpness with CHS100 II.
Mainly acutance effect within the emulsion (PC-512 Borax) and mainly adjacency effects in solution (GSD10 semi stand)"
 

The scanner, which was left on auto re the tones, appears to have decided not to make the RHS sky paper base white, darkening the whole image in the Savoy picture. I did not try to make "best picture".
I believe the sunlight may be the cause of the contrast, here is another pic with rather less contrasty sun:
 
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Even so, the whites look gray on my screens
 
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I did what I believe to be a test of this type in post 26:

"Two forms of apparent sharpness with CHS100 II.
Mainly acutance effect within the emulsion (PC-512 Borax) and mainly adjacency effects in solution (GSD10 semi stand)"

So you did. My apologies.
 
I believe that the reason why developers of the superadditive type don't work too well for producing adjacency effects in stand development is that the primary developing agent ,usually metol or phenidone, gets regenerated. What works better is a single developing agent, as in Rodinal ,also metol and glycin. Of these glycin provides the best freedom from streaking and blotches, see post 63 for a metol comparison.
 

Can you say a bit more about this, possibly with reference to the relevant literature?

Specifically, in (semi)stand you typically agitate twice, once at the beginning and again at the midpoint time. What is your understanding of how the "regeneration" of the metol or phenidone takes place?

I ask because my understanding was that edge effects happen because of the collapse of development activity along the light/dark boundary due to the absence of agitation.

Perhaps I am incorrect.
 

In MQ, adjacency effects caused by the exhaustion of metol are switched off, in PQ the adjacency effects caused by development inhibition effects can be modulated, but don't seem to completely switch off (an issue which can be seen in very specific industry design areas, e.g. late era Agfa BW reversal first developers, where MQ is retained over PQ). Phenidone on its own is capable of very intense, measurable and very visible adjacency effects (if you know where to look you can find what it does to various Kodak emulsions, measured on Kodak's microdensitometry equipment and associated print studies), at a cost of relatively poor emulsion access (i.e. develops some of the emulsion a lot, rather than developing almost all of the available emulsion to a desired degree). Adding a source of semi-quinone resolves the access issue, but does not suppress the adjacency effects as it does in MQ. The P:Q ratio seems to modulate the impact on adjacency effects, and useful ratios for developer design studies can be found in the standard photoengineering manuals for the various phenidones.

The reason you are getting streaking is very likely because modern emulsions are largely structurally designed to release development inhibiting byproducts very readily in most developers (which would include things like Beutler and Rodinal), that when combined with normal agitation patterns (sufficient to ensure even development), should deliver a sharpness level meaningfully comparable to or better than total standstill conditions historically were able to do so. If glycin used as a sole development agent is producing streaks to a lesser extent, it may be because it is less able to access the emulsion/ release the inhibitor byproducts for whatever reason.