I like PMK Pyro best, especially with Tri-X 320 (in 120 size), and often Ilford Pan F+ in either 120 or 135. I don't understand at least one comment on this thread about ruining lots of film while learning to use Pyro. I've had great luck using it, I guess. Pour it in the tank, give it a vigorous twisting inversion once every 15 seconds for about 9 minutes. Use distilled water to mix the developer. Read the Pyro book, which I did, but really, it's a super-easy process. And I don't bother with re-using the developer for the extra staining step. Pictures come out real pretty. I like Diafine and Rodinal, too, but for me, Pyro rules the roost.
Use disposable gloves.