Cyanotype Question/Problem

On the edge of town.

A
On the edge of town.

  • 6
  • 3
  • 85
Peaceful

D
Peaceful

  • 2
  • 11
  • 212
Cycling with wife #2

D
Cycling with wife #2

  • 1
  • 3
  • 90
Time's up!

D
Time's up!

  • 1
  • 1
  • 87

Recent Classifieds

Forum statistics

Threads
198,259
Messages
2,771,849
Members
99,581
Latest member
ibi
Recent bookmarks
0

kevin klein

Member
Joined
Mar 20, 2006
Messages
194
Format
Large Format
The cyanotypes I have been making latly seem to take much longer to expose (two to three times) than they did when I started about eight years ago. Does the dry chemical break down after a few years and not work as well?

Also, what can I do to decrease or increase the contrast?, use more or less of one of the two chemicals?

Thanks.
 

Nicholas Lindan

Advertiser
Advertiser
Joined
Sep 2, 2006
Messages
4,230
Location
Cleveland, Ohio
Format
Multi Format
The Ammonium Iron Citrate does go off. It seems some microbes find it tasty - it must contain enough trace impurities to sustain life.

You might want to try the "New Cyanotype" - it uses Ammonium Iron Oxalate - and is reputed to be more stable. It is, however, a bit of a PITA to make when compared to plain-ole-cyanotype. Contrast can be increased with P. Dichromate.
 

smieglitz

Member
Joined
Oct 18, 2002
Messages
1,950
Location
Climax, Michigan
Format
Large Format
The cyanotypes I have been making latly seem to take much longer to expose (two to three times) than they did when I started about eight years ago. Does the dry chemical break down after a few years and not work as well?

Global warming.

Also, what can I do to decrease or increase the contrast?, use more or less of one of the two chemicals?

Here ya go:

tumblr_m5o6cuSvDK1qmnn9io1_500.jpg


Different ratios of parts A & B on two different varieties of Crane's Kid Finish paper using the traditional cyanotype chemicals (ferric ammonium citrate and potassium ferricyanide). I don't recall which iron salt is 8% and which is 20% solution, but at 1A+1B it is the normal recipe. The strips are arranged 2A+1B, 1A + 1B, 1A + 2B, and then 1A + 1B again (labelled "citric").

It has been a long time since I tested this, so forgive any memory gaps. It looks like this test was done with a NuArc exposure unit at 1120 units for all! Citric acid speeds it up but it bleeds. (Can't remember if this was a pretreatment, addition, or all rinses using 2% citric acid solution but I suspect the latter.) The faint penciled arrows indicate the step to which the exposure solarized before processing. Though I'm not completely sure, I would suspect these were all coated and dried, then exposed and processed together 'cause that's how I roll.
 
Photrio.com contains affiliate links to products. We may receive a commission for purchases made through these links.
To read our full affiliate disclosure statement please click Here.

PHOTRIO PARTNERS EQUALLY FUNDING OUR COMMUNITY:



Ilford ADOX Freestyle Photographic Stearman Press Weldon Color Lab Blue Moon Camera & Machine
Top Bottom