No edge markings= fixer before developer.
I applied a drop of the developer I had used to the leader belonging to this roll, and got the big black dot—assuming that the developer is okay.
No edge markings= fixer before developer.
Contamination causing this sounds odd to me. I would have expected some density and/or fog.
I am no chemist, but I wonder if within those two weeks the developer had deteriorated without showing a big change in color
I am no chemist, but I wonder if within those two weeks the developer had deteriorated without showing a big change in color—Claytons about a month in use appears somewhat “straw" colored, or even slightly beige but has worked.
@TomR55, Do you label your containers?
I have forgotten much of what I learned during 20-some years of working in a clinical laboratory, but one habit still remains. Every container is labeled, and both labels are checked whenever filling one container from another. I won't say I never screw up a roll of film, but I think keeping my containers labeled may have prevented a few cases of mistaken identity in the darkroom. A roll of painter's tape and a Sharpie marker are cheap insurance.
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It was fixed first.
It was fixed first.
I always mix fresh developer for each use in a graduated cylinder. My premixed fixer is in a closed different shaped container labeled with the date. For fixer I use brown glass bottles I got from a pharmacist very many years ago that have been in use for fifty years. I thoroughly clean them each time I make a new mix. I use water from the faucet for stop and a fresh mix of hypoclear each time also in a different shaped container. So far so good. When even labeled containers are the same shape and size it's easy to mix up especially in the dark.
I'm plus one that the film wasn't developed hopefully they weren't important pictures and they can be repeated
I always mix fresh developer for each use in a graduated cylinder. My premixed fixer is in a closed different shaped container labeled with the date. For fixer I use brown glass bottles I got from a pharmacist very many years ago that have been in use for fifty years. I thoroughly clean them each time I make a new mix. I use water from the faucet for stop and a fresh mix of hypoclear each time also in a different shaped container. So far so good. When even labeled containers are the same shape and size it's easy to mix up especially in the dark.
I'm plus one that the film wasn't developed hopefully they weren't important pictures and they can be repeated
You wouldn't be the first person to accidentally fix a roll of film before developing it, no matter how careful you are in laying out your chemistry.
However, if you determined that there are very minimal images present on some frames of the film, then you didn't fix it first - it had to be something awry with the developer; either it has expired or was somehow contaminated. (Do you make a stop bath when developing film? Any chance you accidentally added an acid to the developer, mistaking it for the stop bath container?)
I've never heard of any manufacturer recommending refrigerating a developer to extend its longevity. I don't know that this practice is doing you any favors. The first thing I wondered was whether the cold storage forced an important ingredient to fall out of solution, or somehow be degraded by cold? Dunno. But the thought occurred to me.
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