Doing a "wrong" process, or cross-processing, does not mean wonky colors by definition. Cross-processing E6 film in C-41 indeed results in higher contrast and strange hues, but the high saturation is mostly thanks to high contrast. C-41 film in E6 might be more likely subdued.
But there's also possibility to shoot color neg with long exposures to give enough exposure to shadows and enjoy the very long latitude. Ektar 100 offers remarkable saturation without high contrast, but does not hold up very well for over 1 minute exposures.
These are quite different looks and both are nice and interesting, but in a different way. If I was you, I would try both!
And finally, using slide films such as Velvias as they are intended will also look very good..... If you want fine grain, go with Velvia. Velvia 50 is best IMO for an medium-contrast high-saturation film, but reciprocity failure does not allow exposures much beyond 20 seconds. Velvia 100 and 100F, OTOH, are very good even for long night exposures, but they are higher in contrast.