I may be totally wrong, but I had always understood that toners worked to depletion, and therefore had no actual 'shelf life'. My practice has been to hold on to partially used toner for extended periods - I'm generally not looking for a dramatic color change, so my toners are used very heavily.
I will say that toners work better when warm, and since I usually mix fresh toners with warm water, fresh toners tend to work far more rapidly than toners than have been sitting on the shelf at room temperature. Yes, I know that the solution is to warm them up, and sometimes I do that. I use one of those old immersion heaters that were sold to make single cups of tea.