After the first wash, as we agree, it's a simple diffusion
process depending on the diffusion gradient, but I'd dispute
your assertion that 'pure water diffuses in' which is a bit like
saying 'letting the cold in' rather than 'letting the heat out'.
Yes, water taken up by the gelatine, but this is nothing
to do with the diffusion required for washing, which is
getting the fixer (and fixer products) out.
By the upper portion of that paragraph a vacuum would
form in the emulsion. The lower portion of the above
quoted paragraph makes no sense.
In reality wash water rushes into the emulsion at a rate
dependent upon the concentration gradient and the nature
of the solute within the emulsion. Although the emulsion is
not a classic example of a semi-permeable membrane it
does share some of it's characteristics.
So, an osmotic pressure builds. Reticulation may be induced
and can be intentionally induced. Introduction of the emulsion,
prior to washing, to a warmed solution of high ionic strength
can force an intentional reticulation. Dan
One paper, apparently accommodating hardening fixers
(specifically excluded from the Ilford procedure), advocates
more washing. Surprise. Cheers, R.
Roger;
I don't want this to be a contest.
Fear factor is what causes people to do more than needed such as using wash aids. Remember, they were unknown years ago and there are many fine prints surviving from those days.
So, use what works and don't go overboard. Use tests on the prints. This helps by indicating the state of fixation and wash. You don't have to use wash aids for good results.
PE
All that worries me is the 'fear factor' which always leads to more effort, time and expense in doing something unnecessary, on the specious grounds that if it's more difficult, expensive and time consuming it must also be better -- a not uncommon world-picture, particularly prevalent among some kinds of photographers.
In short, users are advised to ignore poorly tested offhand opinions from places like this thread, but rather follow instructions from manufacturers that test their products and instructions very thoroughly.
As I have said over and over, the emulsion type,
support and thickness all govern wash times.
This is a matter of safety factor.
PE
With all due respect, Ryuji, P. Gainer, P E, Bill Troop, dancqu, Michael and others, what is your verdict?
And why should this final (and absolute) answer not be given a special place on this forum?
Philippe
Well it is apparent that a print's hue also governs
wash time. With regard to the paper in question it
is NOT " ... a matter of safety factor." According to
the Ilford PDF the extended wash is needed to fully
bring forth the warmth of a specific paper. Dan
Well, Roger? Are you up to it?
Have you tested ...? Cheers, R.
For myself I tire of the endless applauding and leaning
upon of such as Levinson and Haist who finished their
work 40 and even 50 years ago. Dan
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