You're probably seeing the effects of the warming filter I reckon. Take it off to record the "actual" hues, if there is such a thing, w/ film/slides, vs what your eye sees. But since everyone see colors somewhat differently, you'll have to live w/ some variations. This is the sort of thing that drove some people batty when photographing their art work. You just have to settle for as close as possible. It never bothered me, because the galleries and I both knew that in order to see the "true" colors you need the piece in front of you, and the color in the piece was highly dependent on the lighting used when viewing it.
Velvia is not known for accurate color reproduction anyway, it's known for super saturated colors.