PXN 5231 is an older film. My latest data sheet for it in in an old PLI and probably dates from sometime in the 80s. I've used the film, and it is excellent for still work. It has very fine grain, decent resolution, and a nice "look", somewhere between the later PX still film and VP. As for use, when in doubt, start with the information on the can. My data sheet lists the speed as 80 daylight and 64 tungsten. The can would normally list the tungsten speed for motion picture film. D-96 is a derivative of D-76, with a little less sulfite, more borax, and a small amount of bromide. D-76 was the standard motion picture negative developer for years, and you can use it perfectly well. Starting times and dilution should be the same as for D-96, and you can adjust from there. Motion picture negatives film is usually somewhat less contrasty than its still film equivalent, so somewhat extended development (probably no more than 10 percent) may be in order.
Kodak D-96 motion picture negative developer
Water (50C) 750 ml
Metol 2 g
Sodium sulfite (anh) 75 g
Hydroquinone 1.5 g
Potassium bromide 400 mg
or
Sodium bromide 350 mg
Borax (decahydrate) 4.5 g
WTM 1 l
pH at 27C =8.6
Specific gravity at 27C = 1.068