Consider the flange-to-film distance and whether this will allow you to focus at infinity. If you're making a bellows rig then no problem, but mounting a 645 lens on an rb, for example, you will have issues.
In terms of coverage, yes, it'll be tight but doable for some lenses at reasonably close focus, so for macro it's fine. However, apart from the issue of coverage, there may be no sharpness benefit.
If it were me I'd just grab some RB lenses while they're still there aplenty on the market... then you will have enough coverage for basic movements at close focus.