The powder kits likely use sodium thiosulfate instead of ammonium thiosulfate in the fix part. This could give slower, more incomplete fixing.
If you look at the MSDS, these kits use Ammonium Thiosulfate, which does exist in powder form.
Can't speak to the Tetenal, but the Unicolor comes with separate Blix A (fixer) and Blix B (bleach) envelopes. Unless PE or someone of knowledge can tell me otherwise, it seems that one could mix separately and use sequentially.
I am not PE, but trust me you can't make separate bleach and fixer like that. A bleach needs both an oxidizer and a suitable counter ion for the newly formed silver ions. BLIX part A doesn't provide the counter ion, since the Thiosulfate from BLIX part B does that in BLIX. Some weeks ago I wrote an (there was a url link here which no longer exists) how to convert a BLIX kit into a separate bleach and fixer kit.
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