Perhaps a mark from pressure on the film in handling, or from a static spark? I started to suggest it might be a pinhole image of the sun cast by a light leak in the bellows, but to be that small, it would have to be cast from a point very close to the film -- within a couple inches, in fact -- and in any case would require the sun be shining on the bellows in a direction that could reach the film, while the dark slide was out. Alternately, a drop of some fogging chemical that landed on the emulsion, either before or after exposure, would give the same effect -- brown or selenium toner could do it, badly decomposed fixer might (sulfur is a strong foggant), and there are a few other chemicals around that could. A droplet of developer could do it, if you tray process your sheet film, causing gross overdevelopment of a very small region.