I've had stock solutions stored for 3 or 4 years and still working well, Iv'e had the W/S solutions stored in plastic bottles for 12 to 18 months, still working well, so to me it seems that both the stock and WS solutions keep well, I test the W/S with an old print, maybe a test print or something before I commit a good print, if it is still working I use it, if not then mix up fresh,
As above i haven't any scientfic tests, just my many years of practical experiance