I did a similar thing where I had to reline the inside of a cracked, yellowed mixing box in a Meopta meochrom color head. I used a high quality artists acrylic in titanium white and applied a few coats of it using a brush. It seemed to work pretty well. I don't know if the performance is as good as what the mixing box would've been new, but it was definitely better than the degraded surface. I got at least a couple of stops more light. If I did it again, I would've used a better brush (or spray) and made sure the coat was perfectly smooth, as it was it was pretty rough. Not sure how much difference that would've made though.
As far as heat resistance goes, it's only relatively early days. I did a stack of printing with it straight after and everything seemed fine, but I haven't used it for a while. If it degrades, it's not going to be hugely difficult to do it again though.
If you find any more suitable paint, I'd love to know actually.