Splotches on negatives -- thoughts?

bdial

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With laminar flow, lids on or off while tapping, etc we're grasping at straws here. But here's another, are the reels exposed to fixer powder when you are mixing it?
 
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With laminar flow, lids on or off while tapping, etc we're grasping at straws here. But here's another, are the reels exposed to fixer powder when you are mixing it?

I use Kodafix liquid fixer concentrate.

I agree it's an exercise in grasping as straws. For what I am doing, it's not been so bad as to ruin a negative, but it would be nice to know what is causing the problem.

Sanders
 

Bob Carnie

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Grasping at Straws??
Shoot some grey cards, adjust your methods in a controlled way.
If you are a professional selling your work on grey backgrounds , I would think you want to solve immediately minus density marks on a nuetral background.
This is a common problem that photographers need to control if they process their own film.
At our lab we have had every type film problem that you could imagine, I agree it is extremely hard to locate the culprit, but spending a couple of days with grey backgrounds and testing different approaches when problems occur is part of our job.
My 2cents is that your initial agitation * in the Developer*is not complete enough and you are getting minus density on your edges of the negs.
If you are using a proper stop, how could it be the fixer?
This is a problem that only you can solve with testing. I don't think anyone here *myself included* can answer this one.


I use Kodafix liquid fixer concentrate.

I agree it's an exercise in grasping as straws. For what I am doing, it's not been so bad as to ruin a negative, but it would be nice to know what is causing the problem.

Sanders
 
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Grasping at Straws?? Shoot some grey cards, adjust your methods in a controlled way. ... This is a problem that only you can solve with testing. I don't think anyone here *myself included* can answer this one.

Bob, I'll go you one further: I don't think it can be solved, period.

So much of the art of film development is just that: Art. No one has much of a clue what really goes on inside of the tank. Witness the explanations various people have provided for how they solved the problem. Some of the explanations could not possibly have changed the outcome they were experiencing. But they did something different, and the problem stopped. It might not have stopped for any reason at all related to the change -- an association does not prove a cause. Or the change observed might have been accompanied by a change unobserved, which in fact was the agent of the solution.

FWIW, I'm betting on an irregularity in the emulsion. That would explain the manifestation only at one edge of the film. I've been doing the processing the same way, with the same film and chemicals and water, for years now. The only change in my case is rotary agitation in the fix instead of inversion. As you say, I have a hard time understanding how that could be the culprit.

One way or another, it will go away. But I won't fool myself into thinking that I ever really knew the problem, or that I overcame it by scientific observation.

Sanders
 

Mike Té

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Not enough developer/fixer: I fill my tanks to overflowing.

If you're filling to overflow, could it be that therefore there's no room for a layer of air at the top? This would diminish the effect of the agitation "wave" that occurs within the tank during inversions, leading to inadequate mixing.

Could your right side edge be the bottom-most edge within the tank, a place where, in the above circumstances, agitation would have the least effect?
 
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If you're filling to overflow, could it be that therefore there's no room for a layer of air at the top? This would diminish the effect of the agitation "wave" that occurs within the tank during inversions, leading to inadequate mixing.

Mike, I believe (and since I can't see inside the tank, the verb here is "believe") that the agitation comes from the reels sliding up and down inside the tank, through the chemical. I do not believe that "wave action" explains it. But it is only a belief.

Sanders
 

Bob Carnie

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Sanders

Blaming the film emulsion is the easiest route to go . If that works for you .
I personally would do some of the testing that I and others have suggested.

Why did you start this thread anyways if you are not prepared to do the legwork?
 

Mike Té

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OK. I fill the tank with reels, one or two empty ones if I have to, so that the reel(s) with film don't peek over the top level of chemical. No sliding.
 

Mike Té

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Here's another thought...

If you have some chemical contamination on your dominant thumb (sometimes a chemical can be well-absorbed into the skin), it would enter into contact with one side of the film as you load....

Well, COULD, rather than WOULD.
 

AgX

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Aside from that splotches,
I read something of aminoacids in sweat reducing the halide in wet collodion processes.
But I also saw a quotation of an Agfa brochure (1958) concerning females' sweat during menstruation. But as this seems to be a rather male group...
 
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Blaming the film emulsion is the easiest route to go . If that works for you. I personally would do some of the testing that I and others have suggested. Why did you start this thread anyways if you are not prepared to do the legwork?

Bob, why the confrontational tone? I was only taking your idea a step further, to what I believe was its logical (and necessary) conclusion.

The problem is that I have already done the things the others suggested. Of course I will now go and vary each of the steps of my processing. Each step has been refined through years of processing many many thousands of rolls of film, without ever observing this problem before. But I will now abandon each, one by one, and see what happens. And somewhere in the process the problem will go away, and whatever it was I changed, I will now incorporate into my workflow. Of course I will do all of that.

But will what I change, be the solution to the problem? Or will it (more likely) merely coincide with some other unseen change? Then I will have committed to practice some false solution to a problem that did not exist. Darkroom practice is rife with stuff like this. How many chestnuts about processing film are created in just this way?

You suggest that attributing it to the emulsion is a cop-out. I suspect it is the most plausible explanation. But that is only my suspicion, based on the location of the splotches. It's too bad PE isn't reading this thread. It would be interesting to read his thoughts on the subject.

Why did I start the thread? Because I had hoped that maybe, someone, somewhere, had seen just this artifact, and could attribute it concretely to a specific problem. Alas, only half my hopes were fulfilled.

Sanders
 

Bob Carnie

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Sanders
Maybe just a bit testy because I don't think you are working hard enough to solve the problem.
Have you done all the tests?
I will agree it is very , very difficult to sort out a film issue, specifically when you incorporate grey backdrops into your workflow.
Yes , I do believe blaming the manufacturer is a cop out, We have always found these types of problems to be with *operator error*.
You will solve this problem and move on , I just hope you can isolate the real reason for the minus density on your negative.
good luck


 
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I went back and reread Aurelien's earlier thread:

(there was a url link here which no longer exists)

He reports seeing the same effect (a strip of splotches along the right rebate) in all three rolls, processed together -- of different films. Assuming it is the same effect, that suggests several things:

-- It isn't a flaw in the film emulsion.

-- It isn't due to something happening at the top of the tank (foam, too little developer, too much developer).

-- It is odd enough that the effect is seen only on one edge, but odder still that it is seen always at the right rebate. One would expect to see it at the left rebate half the time, if it were a development problem.

I am beginning to wonder if it is an exposure artifact or some sort, rather than a development artifact. I am shooting a Rolleiflex. Aurelien's example comes from a Rolleiflex. There is a toothed wheel on that side of the camera that tracks the film for the frame counter. It bites the film in the rebate, but maybe it sometimes deflects the film enough to affect exposure. Maybe not.

Sanders
 
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I do believe blaming the manufacturer is a cop out.

Don't get me wrong: I am a huge defender of Kodak products (if not Kodak management). I shoot only Kodak film, and I use Kodak chemicals. One reason is because they strike me as incredibly consistent and free of manufacturing irregularities. But no human process is perfect. In attempting to isolate a problem, it is irrational to exclude the possibility that the product, however reliable, might be flawed.

Sanders
 

Mike Té

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Or else the reels (one side down, obviously) were waiting on a work surface to be loaded... and on that work surface is a minute sheen of invisible dried chemical of some sort that was wiped up at the last session....

Such a small amount is picked up, but enough to contaminate the film's edge.
 

Bob Carnie

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Sanders

Ok now you are getting somewhere. I was hesitant to say the minus density looked like sprocket holes as it was obvious to me that he was using a medium format camera. I did not know that the camera you and he are using produces sprocket holes.
Just wrap your head around minus density rather than plus density and you may be closer to solving your problem.
Adjacent problems close to edges of film and sprocket holes are prevelant in 35mm work.

 
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Bob, a Rolleiflex TLR doesn't make "sprocket holes" but the toothed roller for the frame counter does indent the film slightly in the right rebate. Questions:

--Any other Rolleiflex users out there with this problem?

--Anyone experiencing the problem without a Rolleiflex?

--Anyone seeing it someplace on the negative other than at the right rebate?

Sanders
 

bdial

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I think the area with the marks would have gone through the left side of the camera.
 
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dr5chrome

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..this is not a film problem, it is a processing problem. If you are not using consistent water [Di or bottled], changes in the tap water will change your outcome. Something in the water is causing a change in process, in turn causing the bubbles to become stubborn at the top of the reel [ re; dr5 processing in NYC pre-D&D processor - hand line]. I have seen and experienced this problem on many occasions. If you have 'stuff' in the water you may not ever get rid of this problem until it works its way out of the pipes. The only thing you can do is agitate as bob suggests. you can also try a spiral agitation 'against' the spiral of the reeled film forcing solution into stubborn areas. you can also try a pre-soak before development. For grins a giggles try a rapid fix, i dont think this is a fix problem however.
Bob and I both process film for a living, we have stated this problem. I have experienced this problem, in NYC to boot, as a shooter and a film processor.

good luck

regards
dw

www.dr5.com
 
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..this is not a film problem, it is a processing problem.

Dave, I respect your opinion. But I have a hard time seeing how it is a processing problem. If it is a processing problem, then how come the splotches always occur at the right rebate? The reels can go into the tank either-side up. It strikes me as a vanishingly-small probability that they always go in with the right rebate on top. (Or on bottom.) What, in your opinion, is going on inside the tank to confine the splotches to the right rebate?

Best,

Sanders
 

AgX

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terminology

Sander,

I consider this discussion very interesting but am somewhat left in the dark…

Please be so kind and define what you mean by `rebate´. If I ever came about it, it has not stuck to my memory. From where I now sit with my laptop in front I have no access to my photographic dictionaries, but I went through several general dictionaries, as well as literature from the photographic industry. No result what could fit.
 

Mick Fagan

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AgX, my German isn't that good but possibly, "perforierter streifen" or "filmperforation"

A rebate is the edge of the film which does not normally receive any light, usually it is used as a transport part of the film, like 135 where the sprocket holes are.

Mick.
 
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