The reusability of digital makes it so much more practical for scientific use, and was embraced fairly quickly in the field as the technology became available.
I know film was used for the earliest spy satellites, and some of the early orbital projects looking back at earth, but I can't recall any programs off the top of my head that used film for any kind of orbital telescopes looking outward.
Consistency is a bit of an issue - "Is that some new and interesting bit of science, or a flaw in the film?"
Data processing is also a problem with film - We pretty much have to digitize the stuff to do serious modern number crunching as it is, so starting from a film base is kind of adding extra steps to the process without gaining much.
And we very much used film for astronomy for a long time, and a lot of ground based observation was still being done with film up through the 90s and 00's. But the only ones still using film that I'm aware of are doing it purely for artistic rather than scientific reasons, simply because digital has proven to be the far better data collection method, and was therefore adopted as quickly as funding became available or prices of equipment dropped enough.
Got any rough idea about what would be involved in altering their trajectories so as to allow a return to Earth's orbit, and whether they could've returned before Dwayne's shut down their Kodachrome processing?
I've possibly messed up my napkin math, but I'm not seeing a way to get them out to Saturn such that they would loop back to earth in anything remotely short enough time. (excluding making them stupidly large with excessive fuel to just about-face and burn back to earth... But they get stupidly larger still if you want them to have enough fuel to slow down when they get here... On a random note, geeky minds should consider trying the game Kerbal Space Program if they haven't seen it before.)