I've got an EOS 90D, which is 32.5 MP and APS-C. If the sensor were expanded to full-frame, it would be approximately 64.5 MP.
It already has issues with the sensor having more detail than a number of older lenses can resolve, and due to pixel site size, suffers from diffraction effects as wide as f/8 on the red channel. It's suspected that Canon is doing some mathematical trickery to reduce this effect, but the pixel density for 102 MP even on full frame, is going to cause issues.