Don, I'm unsure if this will help you with color matching, though I do have an idea as how to go about color mathing...(haven't done it myself yet!)
With the Datacolor printfix pro unit, when calibrating it for a certain printer for the inks you have, the application outputs a sheet of "color steps" for all inks. You then match that with the spectrometer. The application then creates an ICC profile for that paper/ink combination (it performs some sort of magical routine to get your colors looking the best they can!, I'm unsure how this transofrmation takes places in the application?).
So using that same process we can go ahead and create our own print out via the tri color gum way. You'd have to capture the "color steps" output digitally to a file, from there you make sep negs. Follow the same steps you'd make a tri color image of the "color step" digital output file. Then analyze with your spectrometer, and creating an overall ICC profile. Thats it!
This ICC profile can then be applied to whatever image via Photoshop, in the "Assign or Converting image to Profile"..
Then do whatever you do to make your tri color gum.
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Is it this straight forward? I have no idea, never tried it. But it makes sense!