Yep, you could go ahead with that recipe. There's not much risk of overdoing it, it's going to be a relatively minor change anyway. As with any toning exercise, it's wise to test first on something unimportant and to have an untoned reference to look at as you go.
As an alternative that may give you what you want: you could also make another print but deliberately overexpose it by a stop or so, and bleach it back (farmers). That will introduce contrast... and preserve the pristine state of your neg. I mean, if your neg is nice for lith then why change it if you don't have to....
If grade 5 isn't giving enough pop then I guess you misexposed the shot? Is it too thick or too thin overall? If the former then bleaching the neg may be a better option. The change you get from Se is quite minor, and really only makes much of a difference if the starting neg is well exposed. It's definitely not a way to save a neg, in other words. I mean, best case, it's probably going to give maybe a half grade or so of extra contrast if the neg was properly exposed in the first place. I only tone my negs if they are already really close but just need a tiny bit more.