That was my first C41 product, as well. I believe it is Fuji chemistry. As you can see in the table your 45°C is seperated from the other temperatures and labeled as rapid. I guess they offer this combination for those who require a short time. Technically speaking only the 37.8°C will give perfect results. That is because colour film is a stack of three films. For perfect results the three layers contrasts need to match, and it does that at the official temperature. Deviate and you may or may not like the result.
Personally I bought this kit because I was afraid of having to process hat 38° and thought it'd be easier at 30°C or so. But it turns out that it is easier to hold the 37.8°C for 3:15min than 30°C for a longer time. Maybe that is why you'd like to work at 45°C.
So, yes. You should work at 38°C, but if you are happy with the results at 45°C and like that workflow better then keep at it.