I often use 5mL in a 250mL tank.
5ml in 250ml is 1:50.
The problems arise when there's too little developing agent and exhaustion causes compression of the high-lights.
it's not as simple as it first appears because 5 ml in 250ml for a 35mm film is enough to develop a 35mm film with out exhaustion playing much part, 5ml in 500ml is half the strength but one roll of 120 uses the same amount of developing agents to reach a roughly similar density/gamma (contrast).
The actual amount of developing agents used to process an average roll of film is known, it's used to calculate replenishment rates in some developers.
Once a developer begins to exhaust it can be thought of as acting like a two bathe developer, as it's retains it's alkalinity, where the developing agents exhaust in the high-lights but continue in the shadows.
So having the right amount of developing agent present with Rodinal is critical, below the 1+50 dilution, and it was common to use different dilutions for different contrasts.
Ian